Palladium hydrogenation catalysts based on porous carbon materials derived from poly(vinyl chloride) - Conference attendances

Palladium hydrogenation catalysts based on porous carbon materials derived from poly(vinyl chloride) Conference attendances

Language

Английский

Participant type

Стендовый

Conference

13th European Congress on Catalysis
27-31 Aug 2017 , Florence

Authors

Mironenko Roman Mikhajlovich ¹ , Belskaya Olga Borisovna ¹ , Kryazhev Yurij Gavriilovich ^1,2 , Likholobov Vladimir Aleksandrovich ^1,2

Affiliations

1	Center of New Chemical Technologies of the Federal Research Center Boreskov Institute of Catalysis of Siberian Branch of the Russian Academy of Sciences
2	Omsk Scientific Center SB RAS

The applicability of porous carbon materials obtained by the “chemical” dehydrochlorination of poly(vinyl chloride) as supports for palladium hydrogenation catalysts was demonstrated. The efficiency of the catalysts was evaluated in the liquid-phase hydrogenations of styrene, nitrobenzene, chlorobenzene, benzaldehyde, acetophenone. Although the specific activity of the catalysts was noticeably lower than that of the samples based on carbon nanotubes, the complete conversion of the initial compounds and high selectivity for target products were achieved under mild conditions and at a relatively low palladium content (1.5 %).

Mironenko R.M. , Belskaya O.B. , Kryazhev Y.G. , Likholobov V.A.
Palladium hydrogenation catalysts based on porous carbon materials derived from poly(vinyl chloride)
13th European Congress on Catalysis 27-31 Aug 2017