Palladium hydrogenation catalysts based on porous carbon materials derived from poly(vinyl chloride) - Доклады на конференциях

Palladium hydrogenation catalysts based on porous carbon materials derived from poly(vinyl chloride) Доклады на конференциях

Язык

Английский

Тип доклада

Стендовый

Конференция

13th European Congress on Catalysis
27-31 авг. 2017 , Florence

Авторы

Мироненко Роман Михайлович ¹ , Бельская Ольга Борисовна ¹ , Кряжев Юрий Гавриилович ^1,2 , Лихолобов Владимир Александрович ^1,2

Организации

Центр новых химических технологий Федерального государственного бюджетного учреждения науки "Федеральный исследовательский центр «Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук» (Омский филиал)

Федеральное государственное бюджетное учреждение науки Омский научный центр Сибирского отделения Российской академии наук

The applicability of porous carbon materials obtained by the “chemical” dehydrochlorination of poly(vinyl chloride) as supports for palladium hydrogenation catalysts was demonstrated. The efficiency of the catalysts was evaluated in the liquid-phase hydrogenations of styrene, nitrobenzene, chlorobenzene, benzaldehyde, acetophenone. Although the specific activity of the catalysts was noticeably lower than that of the samples based on carbon nanotubes, the complete conversion of the initial compounds and high selectivity for target products were achieved under mild conditions and at a relatively low palladium content (1.5 %).

Mironenko R.M. , Belskaya O.B. , Kryazhev Y.G. , Likholobov V.A.
Palladium hydrogenation catalysts based on porous carbon materials derived from poly(vinyl chloride)
13th European Congress on Catalysis 27-31 Aug 2017