Low-temperature synthesis of sp 2 -Carbon structures with the use of polyvinylene chlorides-reactive polymers with a conjugation system Научная публикация
Журнал |
Solid Fuel Chemistry
ISSN: 0361-5219 , E-ISSN: 1934-8029 |
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Вых. Данные | Год: 2012, Том: 46, Номер: 5, Страницы: 330-337 Страниц : 8 DOI: 10.3103/S0361521912050060 | ||||
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Реферат:
Chlorine-substituted polymers with a system of conjugated double bonds-polyvinylene chlorides, which form sp 2 -carbon structures under unusually mild conditions, were prepared by the dehydrochlorination of carbon-chain perchloropolymers (chlorinated polyvinyl chloride and a polyvinyl chloride-poly-vinylidene chloride composition) under the action of potassium hydroxide in organic media. The results of the potentiometric titration of the reaction medium in the synthesis of polyvinylene chlorides and the characterization of the products by Raman spectroscopy and thermal analysis with the mass spectrometry of the volatile products of thermal degradation confirmed the formation of polyvinylene chlorides under the selected dehydrochlorination conditions. It was hypothesized that the observed incomplete dehydrochlorination of the perchloropolymers is explained by the stabilization of polyvinylene chloride structures in the process of their formation by donor-acceptor interaction with an alkaline agent; this is consistent with the ability of the resulting polyvinylene chlorides to reversibly bind KON from solutions. © Allerton Press, Inc., 2012.
Библиографическая ссылка:
Kryazhev Y.G.
, Solodovnichenko V.S.
Low-temperature synthesis of sp 2 -Carbon structures with the use of polyvinylene chlorides-reactive polymers with a conjugation system
Solid Fuel Chemistry. 2012. V.46. N5. P.330-337. DOI: 10.3103/S0361521912050060 WOS Scopus РИНЦ
Low-temperature synthesis of sp 2 -Carbon structures with the use of polyvinylene chlorides-reactive polymers with a conjugation system
Solid Fuel Chemistry. 2012. V.46. N5. P.330-337. DOI: 10.3103/S0361521912050060 WOS Scopus РИНЦ
Оригинальная:
Кряжев Ю.Г.
, Солодовниченко В.С.
Низкотемпературный синтез sp2-углеродных структур с использованием полихлорвиниленов реакционноспособных полимеров с системой сопряжения
Химия твердого топлива. 2012. Т.46. №5. С.54-61. РИНЦ
Низкотемпературный синтез sp2-углеродных структур с использованием полихлорвиниленов реакционноспособных полимеров с системой сопряжения
Химия твердого топлива. 2012. Т.46. №5. С.54-61. РИНЦ
Даты:
Опубликована в печати: | 1 сент. 2012 г. |
Опубликована online: | 10 окт. 2012 г. |
Поступила в редакцию: | 6 апр. 2013 г. |
Идентификаторы БД:
Web of science | WOS:000309686300012 |
Scopus | 2-s2.0-84870234284 |
РИНЦ | 20493842 |
OpenAlex | W1991823949 |