Low-temperature synthesis of sp 2 -Carbon structures with the use of polyvinylene chlorides-reactive polymers with a conjugation system Full article
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Solid Fuel Chemistry
ISSN: 0361-5219 , E-ISSN: 1934-8029 |
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Output data | Year: 2012, Volume: 46, Number: 5, Pages: 330-337 Pages count : 8 DOI: 10.3103/S0361521912050060 | ||||
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Abstract:
Chlorine-substituted polymers with a system of conjugated double bonds-polyvinylene chlorides, which form sp 2 -carbon structures under unusually mild conditions, were prepared by the dehydrochlorination of carbon-chain perchloropolymers (chlorinated polyvinyl chloride and a polyvinyl chloride-poly-vinylidene chloride composition) under the action of potassium hydroxide in organic media. The results of the potentiometric titration of the reaction medium in the synthesis of polyvinylene chlorides and the characterization of the products by Raman spectroscopy and thermal analysis with the mass spectrometry of the volatile products of thermal degradation confirmed the formation of polyvinylene chlorides under the selected dehydrochlorination conditions. It was hypothesized that the observed incomplete dehydrochlorination of the perchloropolymers is explained by the stabilization of polyvinylene chloride structures in the process of their formation by donor-acceptor interaction with an alkaline agent; this is consistent with the ability of the resulting polyvinylene chlorides to reversibly bind KON from solutions. © Allerton Press, Inc., 2012.
Cite:
Kryazhev Y.G.
, Solodovnichenko V.S.
Low-temperature synthesis of sp 2 -Carbon structures with the use of polyvinylene chlorides-reactive polymers with a conjugation system
Solid Fuel Chemistry. 2012. V.46. N5. P.330-337. DOI: 10.3103/S0361521912050060 WOS Scopus РИНЦ
Low-temperature synthesis of sp 2 -Carbon structures with the use of polyvinylene chlorides-reactive polymers with a conjugation system
Solid Fuel Chemistry. 2012. V.46. N5. P.330-337. DOI: 10.3103/S0361521912050060 WOS Scopus РИНЦ
Original:
Кряжев Ю.Г.
, Солодовниченко В.С.
Низкотемпературный синтез sp2-углеродных структур с использованием полихлорвиниленов реакционноспособных полимеров с системой сопряжения
Химия твердого топлива. 2012. Т.46. №5. С.54-61. РИНЦ
Низкотемпературный синтез sp2-углеродных структур с использованием полихлорвиниленов реакционноспособных полимеров с системой сопряжения
Химия твердого топлива. 2012. Т.46. №5. С.54-61. РИНЦ
Dates:
Published print: | Sep 1, 2012 |
Published online: | Oct 10, 2012 |
Submitted: | Apr 6, 2013 |
Identifiers:
Web of science | WOS:000309686300012 |
Scopus | 2-s2.0-84870234284 |
Elibrary | 20493842 |
OpenAlex | W1991823949 |