An Unusual Reduction Route of 2,4,6-Trinitrobenzoic Acid under Conditions of Aqueous-Phase Hydrogenation over Pd/Sibunit Catalyst Full article
| Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 2016, Volume: 65, Number: 6, Pages: 1535-1540 Pages count : 6 DOI: 10.1007/s11172-016-1479-8 | ||||||||||
| Tags | 2,4,6-trinitrobenzoic acid, catalytic hydrogenation, palladium catalyst, cyclohexane-1,3,5-trione trioxime | ||||||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 16-03-00601-a |
Abstract:
For the first time it was established that the catalytic hydrogenation of 2,4,6-trinitrobenzoic acid to 1,3,5-triaminobenzene can proceed via the formation of aromatic hydroxyamines and cyclohexane-1,3,5-trione trioxime. As a result of aqueousphase hydrogenation of sodium salt of 2,4,6-trinitrobenzoic acid in the presence of 5%Pd/Sibunit catalyst at a temperature of 323 K and pressure of 0.5 MPa, a trioxime in high yield (about 70 %) was obtained. Due to high selectivity to cyclohexane-1,3,5-trione trioxime the catalytic hydrogenation of sodium salt of 2,4,6-trinitrobenzoic acid can be considered as a new method for its synthesis.
Cite:
Mironenko R.M.
, Belskaya O.B.
, Talzi V.P.
, Rodionov V.A.
, Sysolyatin S.V.
, Likholobov V.A.
An Unusual Reduction Route of 2,4,6-Trinitrobenzoic Acid under Conditions of Aqueous-Phase Hydrogenation over Pd/Sibunit Catalyst
Russian Chemical Bulletin. 2016. V.65. N6. P.1535-1540. DOI: 10.1007/s11172-016-1479-8 WOS Scopus РИНЦ OpenAlex
An Unusual Reduction Route of 2,4,6-Trinitrobenzoic Acid under Conditions of Aqueous-Phase Hydrogenation over Pd/Sibunit Catalyst
Russian Chemical Bulletin. 2016. V.65. N6. P.1535-1540. DOI: 10.1007/s11172-016-1479-8 WOS Scopus РИНЦ OpenAlex
Original:
Мироненко Р.М.
, Бельская О.Б.
, Талзи В.П.
, Родионов В.А.
, Сысолятин С.В.
, Лихолобов В.А.
Необычный путь восстановления 2,4,6-тринитробензойной кислоты в условиях аквафазного гидрирования на катализаторе Pd/сибунит
Известия Академии наук. Серия химическая. 2016. №6. С.1535-1540. РИНЦ
Необычный путь восстановления 2,4,6-тринитробензойной кислоты в условиях аквафазного гидрирования на катализаторе Pd/сибунит
Известия Академии наук. Серия химическая. 2016. №6. С.1535-1540. РИНЦ
Dates:
| Submitted: | Jan 28, 2016 |
| Published print: | Jun 1, 2016 |
| Published online: | Feb 22, 2017 |
Identifiers:
| Web of science: | WOS:000395522500012 |
| Scopus: | 2-s2.0-85013408032 |
| Elibrary: | 29479769 |
| OpenAlex: | W2590357158 |