Conversion of higher n-alkanes under deep catalytic cracking conditions Full article
Journal |
Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532 |
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Output data | Year: 2010, Volume: 50, Number: 5, Pages: 362-367 Pages count : 6 DOI: 10.1134/S0965544110050075 | ||
Tags | Zeolite, Petroleum Chemistry, Strong Acid Site, Isoparaffins, Zeolite, HZSM | ||
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Abstract:
The product distribution for the deep catalytic cracking of C 16-C28 n-alkanes has been studied. Using the method of the temperature-programmed desorption of ammonia, the difference in the acid properties of HZSM-5 and ultrastable Y zeolites and the catalyst matrix components has been found. For the primary cracking of heavy hydrocarbon feedstock to occur, the catalyst matrix must have a high acidity. Bizeolite catalysts exhibit high selectivities for olefins with both normal and branched chains, which are due to a decrease in the contribution of the hydrogen redistribution reaction. For a bizeolite catalyst, the additivity of the selectivities for olefins and aromatic hydrocarbons, depending on the composition of the zeolite component, is observed.
Cite:
Lipin P.V.
, Doronin V.P.
, Gulyaeva T.I.
Conversion of higher n-alkanes under deep catalytic cracking conditions
Petroleum Chemistry. 2010. V.50. N5. P.362-367. DOI: 10.1134/S0965544110050075 WOS Scopus РИНЦ OpenAlex
Conversion of higher n-alkanes under deep catalytic cracking conditions
Petroleum Chemistry. 2010. V.50. N5. P.362-367. DOI: 10.1134/S0965544110050075 WOS Scopus РИНЦ OpenAlex
Original:
Липин П.В.
, Доронин В.П.
, Гуляева Т.И.
Превращение высших н-алканов в условиях глубокого каталитического крекинга
Нефтехимия. 2010. Т.50. №5. С.372-377. РИНЦ
Превращение высших н-алканов в условиях глубокого каталитического крекинга
Нефтехимия. 2010. Т.50. №5. С.372-377. РИНЦ
Dates:
Submitted: | Feb 2, 2010 |
Published print: | Sep 1, 2010 |
Published online: | Oct 5, 2010 |
Identifiers:
Web of science: | WOS:000282512100007 |
Scopus: | 2-s2.0-77958008266 |
Elibrary: | 16672711 |
OpenAlex: | W2056076406 |