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Conversion of higher n-alkanes under deep catalytic cracking conditions Full article

Journal Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532
Output data Year: 2010, Volume: 50, Number: 5, Pages: 362-367 Pages count : 6 DOI: 10.1134/S0965544110050075
Tags Zeolite, Petroleum Chemistry, Strong Acid Site, Isoparaffins, Zeolite, HZSM
Authors Lipin P.V. 1 , Doronin V.P. 1 , Gulyaeva T.I. 1
Affiliations
1 Institute of Problems of Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences, Omsk, Russia

Abstract: The product distribution for the deep catalytic cracking of C 16-C28 n-alkanes has been studied. Using the method of the temperature-programmed desorption of ammonia, the difference in the acid properties of HZSM-5 and ultrastable Y zeolites and the catalyst matrix components has been found. For the primary cracking of heavy hydrocarbon feedstock to occur, the catalyst matrix must have a high acidity. Bizeolite catalysts exhibit high selectivities for olefins with both normal and branched chains, which are due to a decrease in the contribution of the hydrogen redistribution reaction. For a bizeolite catalyst, the additivity of the selectivities for olefins and aromatic hydrocarbons, depending on the composition of the zeolite component, is observed.
Cite: Lipin P.V. , Doronin V.P. , Gulyaeva T.I.
Conversion of higher n-alkanes under deep catalytic cracking conditions
Petroleum Chemistry. 2010. V.50. N5. P.362-367. DOI: 10.1134/S0965544110050075 WOS Scopus РИНЦ OpenAlex
Original: Липин П.В. , Доронин В.П. , Гуляева Т.И.
Превращение высших н-алканов в условиях глубокого каталитического крекинга
Нефтехимия. 2010. Т.50. №5. С.372-377. РИНЦ
Dates:
Submitted: Feb 2, 2010
Published print: Sep 1, 2010
Published online: Oct 5, 2010
Identifiers:
Web of science: WOS:000282512100007
Scopus: 2-s2.0-77958008266
Elibrary: 16672711
OpenAlex: W2056076406
Citing:
DB Citing
Web of science 17
Scopus 18
Elibrary 16
OpenAlex 19
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