Conversion of higher n-alkanes under deep catalytic cracking conditions | Sciact

Conversion of higher n-alkanes under deep catalytic cracking conditions Научная публикация

Журнал

Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532

Вых. Данные

Год: 2010, Том: 50, Номер: 5, Страницы: 362-367 Страниц : 6 DOI: 10.1134/S0965544110050075

Ключевые слова

Zeolite, Petroleum Chemistry, Strong Acid Site, Isoparaffins, Zeolite, HZSM

Авторы

Lipin P.V. ¹ , Doronin V.P. ¹ , Gulyaeva T.I. ¹

Организации

1	Institute of Problems of Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences, Omsk, Russia

The product distribution for the deep catalytic cracking of C 16-C28 n-alkanes has been studied. Using the method of the temperature-programmed desorption of ammonia, the difference in the acid properties of HZSM-5 and ultrastable Y zeolites and the catalyst matrix components has been found. For the primary cracking of heavy hydrocarbon feedstock to occur, the catalyst matrix must have a high acidity. Bizeolite catalysts exhibit high selectivities for olefins with both normal and branched chains, which are due to a decrease in the contribution of the hydrogen redistribution reaction. For a bizeolite catalyst, the additivity of the selectivities for olefins and aromatic hydrocarbons, depending on the composition of the zeolite component, is observed.

Lipin P.V. , Doronin V.P. , Gulyaeva T.I.
Conversion of higher n-alkanes under deep catalytic cracking conditions
Petroleum Chemistry. 2010. V.50. N5. P.362-367. DOI: 10.1134/S0965544110050075 WOS Scopus РИНЦ OpenAlex

Липин П.В. , Доронин В.П. , Гуляева Т.И.
Превращение высших н-алканов в условиях глубокого каталитического крекинга
Нефтехимия. 2010. Т.50. №5. С.372-377. РИНЦ

Поступила в редакцию:	2 февр. 2010 г.
Опубликована в печати:	1 сент. 2010 г.
Опубликована online:	5 окт. 2010 г.

Web of science:	WOS:000282512100007
Scopus:	2-s2.0-77958008266
РИНЦ:	16672711
OpenAlex:	W2056076406

БД	Цитирований
Web of science	17
Scopus	18
РИНЦ	16
OpenAlex	19