Effects of the Carbon Support Nature and Ruthenium Content on the Performances of Ru/C Catalysts in the Liquid-Phase Hydrogenation of Benzaldehyde to Benzyl Alcohol Full article
| Journal |
Monatshefte fur Chemie
ISSN: 1434-4475 , E-ISSN: 0026-9247 |
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| Output data | Year: 2015, Volume: 146, Number: 6, Pages: 923-930 Pages count : 8 DOI: 10.1007/s00706-015-1445-4 | ||||
| Tags | Benzaldehyde, Carbon black, Carbon nanotubes, Heterogeneous catalysis, Hydrogenations, Ruthenium catalysts | ||||
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Abstract:
The hydrogenation of benzaldehyde in ethanol medium in the presence of Ru/C catalysts was shown to proceed with the preferential formation of benzyl alcohol without subsequent hydrodeoxygenation into toluene. An increase in ruthenium content of the catalysts from 0.3 to 1.5 % enhanced the catalytic activity at a high selectivity for benzyl alcohol. The effect of physicochemical characteristics of the support on the formation and catalytic properties of metallic sites in the Ru/C samples was revealed. Most active in the formation of benzyl alcohol were the catalysts containing carbon nanotubes.
Cite:
Mironenko R.M.
, Belskaya O.B.
, Zaikovskii V.I.
, Likholobov V.A.
Effects of the Carbon Support Nature and Ruthenium Content on the Performances of Ru/C Catalysts in the Liquid-Phase Hydrogenation of Benzaldehyde to Benzyl Alcohol
Monatshefte fur Chemie. 2015. V.146. N6. P.923-930. DOI: 10.1007/s00706-015-1445-4 WOS Scopus РИНЦ ANCAN OpenAlex
Effects of the Carbon Support Nature and Ruthenium Content on the Performances of Ru/C Catalysts in the Liquid-Phase Hydrogenation of Benzaldehyde to Benzyl Alcohol
Monatshefte fur Chemie. 2015. V.146. N6. P.923-930. DOI: 10.1007/s00706-015-1445-4 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Oct 22, 2014 |
| Accepted: | Feb 18, 2015 |
| Published online: | Mar 27, 2015 |
| Published print: | May 31, 2015 |
Identifiers:
| Web of science: | WOS:000354242200009 |
| Scopus: | 2-s2.0-84938284861 |
| Elibrary: | 23994373 |
| Chemical Abstracts: | 2015:553720 |
| Chemical Abstracts (print): | 162:563885 |
| OpenAlex: | W1994787841 |