Hydrooligomerization of Unsaturated Hydrocarbons as a Basis of New Technologies for the Production of Motor Fuel Compounds Full article
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Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2017, Volume: 9, Number: 4, Pages: 308-316 Pages count : 9 DOI: 10.1134/S2070050417040055 | ||||
| Tags | borate-containing alumina, nickel oxide, palladium oxide, molybdenum oxide, hydrooligomerization, butenes, acetylene, motor fuels | ||||
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 46.2.5 |
Abstract:
A brief analysis is performed for the current state of processes for the production of motor fuels based on the consecutive oligomerization and hydrogenation reactions of unsaturated hydrocarbons. Some new butene hydrooligomerization catalysts based on the bifunctional NiO/В2O3–Al2O3, PdO/В2O3–Al2O3, and MoO3/В2O3–Al2O3 systems are considered. It is shown that the best process performance parameters (a 67 wt % yield of liquid С5+ products at a butene conversion of more than 90%) are achieved with PdO/В2O3–Al2O3 catalyst prereduced in a hydrogen medium. The possibility of acetylene hydrooligomerization on NiO/B2O3–Al2O3 catalyst is demonstrated in principle. It is stablished that the presence of nickel(II) cations chemically bonded to the surface of a support is of fundamental importance for both acetylene hydrooligomerization and ethylene oligomerization.
Cite:
Karpova T.R.
, Buluchevskii E.A.
, Lavrenov A.V.
Hydrooligomerization of Unsaturated Hydrocarbons as a Basis of New Technologies for the Production of Motor Fuel Compounds
Catalysis in Industry. 2017. V.9. N4. P.308-316. DOI: 10.1134/S2070050417040055 WOS Scopus РИНЦ OpenAlex
Hydrooligomerization of Unsaturated Hydrocarbons as a Basis of New Technologies for the Production of Motor Fuel Compounds
Catalysis in Industry. 2017. V.9. N4. P.308-316. DOI: 10.1134/S2070050417040055 WOS Scopus РИНЦ OpenAlex
Original:
Карпова Т.Р.
, Булучевский Е.А.
, Лавренов А.В.
Гидроолигомеризация непредельных углеводородов - основа новых технологий получения компонентов моторных топлив
Катализ в промышленности. 2017. Т.17. №3. С.220-227. DOI: 10.18412/1816-0387-2017-3-220-227 РИНЦ OpenAlex
Гидроолигомеризация непредельных углеводородов - основа новых технологий получения компонентов моторных топлив
Катализ в промышленности. 2017. Т.17. №3. С.220-227. DOI: 10.18412/1816-0387-2017-3-220-227 РИНЦ OpenAlex
Dates:
| Submitted: | Dec 19, 2016 |
| Published print: | Oct 1, 2017 |
| Published online: | Dec 16, 2017 |
Identifiers:
| Web of science: | WOS:000423241900004 |
| Scopus: | 2-s2.0-85038218837 |
| Elibrary: | 35479816 |
| OpenAlex: | W2775393404 |
Citing:
| DB | Citing |
|---|---|
| OpenAlex | 1 |