Hydrooligomerization of Unsaturated Hydrocarbons as a Basis of New Technologies for the Production of Motor Fuel Compounds

Hydrooligomerization of Unsaturated Hydrocarbons as a Basis of New Technologies for the Production of Motor Fuel Compounds Научная публикация

Журнал

Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555

Вых. Данные

Год: 2017, Том: 9, Номер: 4, Страницы: 308-316 Страниц : 9 DOI: 10.1134/S2070050417040055

Ключевые слова

borate-containing alumina, nickel oxide, palladium oxide, molybdenum oxide, hydrooligomerization, butenes, acetylene, motor fuels

Авторы

Karpova T. R. ¹ , Buluchevskii E. A. ^1,2 , Lavrenov A. V. ¹

Организации

1	Institute of Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences
2	Dostoevsky Omsk State University

Информация о финансировании (1)

Министерство науки и высшего образования Российской Федерации

46.2.5

A brief analysis is performed for the current state of processes for the production of motor fuels based on the consecutive oligomerization and hydrogenation reactions of unsaturated hydrocarbons. Some new butene hydrooligomerization catalysts based on the bifunctional NiO/В2O3–Al2O3, PdO/В2O3–Al2O3, and MoO3/В2O3–Al2O3 systems are considered. It is shown that the best process performance parameters (a 67 wt % yield of liquid С5+ products at a butene conversion of more than 90%) are achieved with PdO/В2O3–Al2O3 catalyst prereduced in a hydrogen medium. The possibility of acetylene hydrooligomerization on NiO/B2O3–Al2O3 catalyst is demonstrated in principle. It is stablished that the presence of nickel(II) cations chemically bonded to the surface of a support is of fundamental importance for both acetylene hydrooligomerization and ethylene oligomerization.

Karpova T.R. , Buluchevskii E.A. , Lavrenov A.V.
Hydrooligomerization of Unsaturated Hydrocarbons as a Basis of New Technologies for the Production of Motor Fuel Compounds
Catalysis in Industry. 2017. V.9. N4. P.308-316. DOI: 10.1134/S2070050417040055 WOS Scopus РИНЦ OpenAlex

Карпова Т.Р. , Булучевский Е.А. , Лавренов А.В.
Гидроолигомеризация непредельных углеводородов - основа новых технологий получения компонентов моторных топлив
Катализ в промышленности. 2017. Т.17. №3. С.220-227. DOI: 10.18412/1816-0387-2017-3-220-227 РИНЦ OpenAlex

Поступила в редакцию:	19 дек. 2016 г.
Опубликована в печати:	1 окт. 2017 г.
Опубликована online:	16 дек. 2017 г.

Web of science:	WOS:000423241900004
Scopus:	2-s2.0-85038218837
РИНЦ:	35479816
OpenAlex:	W2775393404

БД	Цитирований
OpenAlex	1