Abstract: Pd/SO42-/ZrO2/Al2O3catalysts are prepared and investigated in reaction of isomerization of N-hexane in the work. For comparison Pt/SO42-/ZrO2/Al2O3 catalysts are investigated. It is established that in the field of low temperatures (140 °C) the catalyst on the basis of palladium shows high rates comparable to the Pt-containing catalyst. At more high temperatures yield of isomers for Pd/SO42-/ZrO2/Al2O3 catalyst are lower, than for Pt/SO42-/ZrO2/Al2O3. However, isomerization depth (the maintenance of a 2, 2-dimetilbutan in mix of C6 isomers) for the palladic catalyst in all studied range of temperatures exceeds for 6-10% a similar indicator for the platinum catalyst. For clarification of the role of condition of palladium the catalysts Pd/Al2O3, Pd/SiO2 were prepared and investigated. It was established that the best indicators are reached on the aluminum oxide systems in which palladium is in the oxidized state

Cite: Dzhikiya O.V. , Smolikov M.D. , Zatolokina E.V. , Kazantsev K.V. , Belyi A.S.
Investigation of Palladium Catalysts in n-hexane Isomerization Reaction
Procedia Engineering. 2015. V.113. P.98-102. DOI: 10.1016/j.proeng.2015.07.299 WOS Scopus РИНЦ OpenAlex

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Identifiers:

Web of science:	WOS:000380445300017
Scopus:	2-s2.0-84984870505
Elibrary:	26801347
OpenAlex:	W2250543159

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