Sciact
  • EN
  • RU

Investigation of Palladium Catalysts in n-hexane Isomerization Reaction Научная публикация

Конференция 5-ая международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства"
25-30 апр. 2015 , Омск
Журнал Procedia Engineering
ISSN: 1877-7058
Вых. Данные Год: 2015, Том: 113, Страницы: 98-102 Страниц : 5 DOI: 10.1016/j.proeng.2015.07.299
Ключевые слова palladium; sulfated zirconia; n-hexane isomerization
Авторы Dzhikiya O.V. 1 , Smolikov M.D. 1,2 , Zatolokina E.V. 1 , Kazantsev K.V. 1 , Belyi A.S. 1,2
Организации
1 Institute of Hydrocarbon Processing
2 Omsk State Technical University

Реферат: Pd/SO42-/ZrO2/Al2O3catalysts are prepared and investigated in reaction of isomerization of N-hexane in the work. For comparison Pt/SO42-/ZrO2/Al2O3 catalysts are investigated. It is established that in the field of low temperatures (140 °C) the catalyst on the basis of palladium shows high rates comparable to the Pt-containing catalyst. At more high temperatures yield of isomers for Pd/SO42-/ZrO2/Al2O3 catalyst are lower, than for Pt/SO42-/ZrO2/Al2O3. However, isomerization depth (the maintenance of a 2, 2-dimetilbutan in mix of C6 isomers) for the palladic catalyst in all studied range of temperatures exceeds for 6-10% a similar indicator for the platinum catalyst. For clarification of the role of condition of palladium the catalysts Pd/Al2O3, Pd/SiO2 were prepared and investigated. It was established that the best indicators are reached on the aluminum oxide systems in which palladium is in the oxidized state
Библиографическая ссылка: Dzhikiya O.V. , Smolikov M.D. , Zatolokina E.V. , Kazantsev K.V. , Belyi A.S.
Investigation of Palladium Catalysts in n-hexane Isomerization Reaction
Procedia Engineering. 2015. V.113. P.98-102. DOI: 10.1016/j.proeng.2015.07.299 WOS Scopus РИНЦ OpenAlex
Файлы: Полный текст от издателя
Идентификаторы БД:
Web of science: WOS:000380445300017
Scopus: 2-s2.0-84984870505
РИНЦ: 26801347
OpenAlex: W2250543159
Цитирование в БД:
БД Цитирований
Web of science 2
Scopus 2
РИНЦ 3
OpenAlex 2
Альметрики: