Investigation of the Pt/MOR–Al2O3 Catalysts by IR Spectroscopy Full article
Conference |
5-ая международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства" 25-30 Apr 2015 , Омск |
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Journal |
Procedia Engineering
ISSN: 1877-7058 |
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Output data | Year: 2015, Volume: 113, Pages: 19-25 Pages count : 7 DOI: 10.1016/j.proeng.2015.07.281 | ||||||
Tags | platinum; mordenite; alumina; FTIR CO and NH3; DRIFT CO; cyclohexane; benzene; hydroisomerization | ||||||
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Abstract:
Pt/MOR–Al2O3 catalysts, with platinum supported from H2PtCl6 and [Pt(NH3)4]Cl2 solutions are investigated in the work with the methods of IR spectroscopy. The received results testify about platinum fixing mainly in channels of a mordenite in case of supporting from an ammine, and its localization on Al2O3 surface when supporting from chloroplatinic acid. Small concentration of the absorption bands referred to bridging CO species on platinum testify about high dispersion of metal on samples. Data explain higher activity of the catalysts prepared with [Pt(NH3)4]Cl2 in reactions of a hydroisomerization of benzene and an isomerization of cyclohexane.
Cite:
Belopukhov E.A.
, Paukshtis E.A.
, Shkurenok V.A.
, Smolikov M.D.
, Belyi A.S.
Investigation of the Pt/MOR–Al2O3 Catalysts by IR Spectroscopy
Procedia Engineering. 2015. V.113. P.19-25. DOI: 10.1016/j.proeng.2015.07.281 WOS Scopus РИНЦ OpenAlex
Investigation of the Pt/MOR–Al2O3 Catalysts by IR Spectroscopy
Procedia Engineering. 2015. V.113. P.19-25. DOI: 10.1016/j.proeng.2015.07.281 WOS Scopus РИНЦ OpenAlex
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Identifiers:
Web of science: | WOS:000380445300004 |
Scopus: | 2-s2.0-84988299006 |
Elibrary: | 27576574 |
OpenAlex: | W1111595127 |