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Investigation of the Pt/MOR–Al2O3 Catalysts by IR Spectroscopy Научная публикация

Конференция 5-ая международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства"
25-30 апр. 2015 , Омск
Журнал Procedia Engineering
ISSN: 1877-7058
Вых. Данные Год: 2015, Том: 113, Страницы: 19-25 Страниц : 7 DOI: 10.1016/j.proeng.2015.07.281
Ключевые слова platinum; mordenite; alumina; FTIR CO and NH3; DRIFT CO; cyclohexane; benzene; hydroisomerization
Авторы Belopukhov E.A. 1 , Paukshtis E.A. 2 , Shkurenok V.A. 1 , Smolikov M.D. 1,3 , Belyi A.S. 1,3
Организации
1 Institute of Hydrocarbons Processing SB RAS, 54, Neftezavodskaya St., Omsk 644040, Russian Federation
2 Boreskov Institute of Catalysis SB RAS, Lavrentieva Av. 5, Novosibirsk, 630090, Russian Federation
3 Omsk State Technical University, 11, Mira Pr.,, Omsk 644050, Russian Federation

Реферат: Pt/MOR–Al2O3 catalysts, with platinum supported from H2PtCl6 and [Pt(NH3)4]Cl2 solutions are investigated in the work with the methods of IR spectroscopy. The received results testify about platinum fixing mainly in channels of a mordenite in case of supporting from an ammine, and its localization on Al2O3 surface when supporting from chloroplatinic acid. Small concentration of the absorption bands referred to bridging CO species on platinum testify about high dispersion of metal on samples. Data explain higher activity of the catalysts prepared with [Pt(NH3)4]Cl2 in reactions of a hydroisomerization of benzene and an isomerization of cyclohexane.
Библиографическая ссылка: Belopukhov E.A. , Paukshtis E.A. , Shkurenok V.A. , Smolikov M.D. , Belyi A.S.
Investigation of the Pt/MOR–Al2O3 Catalysts by IR Spectroscopy
Procedia Engineering. 2015. V.113. P.19-25. DOI: 10.1016/j.proeng.2015.07.281 WOS Scopus РИНЦ OpenAlex
Файлы: Полный текст от издателя
Идентификаторы БД:
Web of science: WOS:000380445300004
Scopus: 2-s2.0-84988299006
РИНЦ: 27576574
OpenAlex: W1111595127
Цитирование в БД:
БД Цитирований
Scopus 10
Web of science 9
РИНЦ 5
OpenAlex 9
Альметрики: