Rapid “Mix-and-Stir” Preparation of Well-Defined Palladium on Carbon Catalysts for Efficient Practical Use

Rapid “Mix-and-Stir” Preparation of Well-Defined Palladium on Carbon Catalysts for Efficient Practical Use Full article

Journal

ChemCatChem
ISSN: 1867-3880 , E-ISSN: 1867-3899

Output data

Year: 2018, Volume: 10, Number: 8, Pages: 1869-1873 Pages count : 5 DOI: 10.1002/cctc.201700738

Tags

carbon, cross-coupling, hydrogenation, palladium, supported catalysts

Authors

Yakukhnov Sergey A. ¹ , Pentsak Evgeniy O. ¹ , Galkin Konstantin I. ¹ , Mironenko Roman M. ² , Drozdov Vladimir A. ² , Likholobov Vladimir A. ² , Ananikov Valentine P. ¹

Affiliations

1	Zelinsky Institute of Organic Chemistry Russian Academy of Sciences
2	Institute of Hydrocarbon Processing Russian Academy of Sciences, Siberian Branch

Funding (1)

Russian Science Foundation

14-13-01030

A facile direct deposition approach for the preparation of recyclable Pd/C catalysts simply by stirring a solution of tris(dibenzylideneacetone)dipalladium(0) with a suitable carbon material was evaluated. An extraordinarily rapid catalyst preparation procedure (<5 min) under mild conditions and its excellent performance in cross-coupling and hydrogenation reactions were demonstrated. The key point for catalyst design is the direct deposition of Pd0 centers onto the highly accessible surface area and the avoidance of ill-defined PdII/Pd0 states.

Yakukhnov S.A. , Pentsak E.O. , Galkin K.I. , Mironenko R.M. , Drozdov V.A. , Likholobov V.A. , Ananikov V.P.
Rapid “Mix-and-Stir” Preparation of Well-Defined Palladium on Carbon Catalysts for Efficient Practical Use
ChemCatChem. 2018. V.10. N8. P.1869-1873. DOI: 10.1002/cctc.201700738 WOS Scopus РИНЦ OpenAlex

Submitted:	May 3, 2017
Accepted:	Jun 26, 2017
Published online:	Oct 10, 2017
Published print:	Apr 24, 2018

Web of science:	WOS:000430659500022
Scopus:	2-s2.0-85045892094
Elibrary:	35540717
OpenAlex:	W2667977495

DB	Citing
Scopus	39
Web of science	34
OpenAlex	44