The phenomenon of “dead” metal in heterogeneous catalysis: opportunities for increasing the efficiency of carbon-supported metal catalysts Review
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Chemical Science
ISSN: 2041-6520 |
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| Output data | Year: 2023, Volume: 14, Number: 48, Pages: 14062-14073 Pages count : 12 DOI: 10.1039/D3SC04691E | ||||||||
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0004 |
Abstract:
This review addresses the largely overlooked yet critical issue of “dead” metal in heterogeneous metal catalysts. “Dead” metal refers to the fraction of metal in a catalyst that remains inaccessible to reactants, significantly reducing the overall catalyst performance. As a representative example considered in detail here, this challenge is particularly relevant for carbon-supported metal catalysts, extensively employed in research and industrial settings. We explore key factors contributing to the formation of “dead” metal, including the morphology of the support, metal atom intercalation within the support layers, encapsulation of metal nanoparticles, interference by organic molecules during catalyst preparation, and dynamic behavior under microwave irradiation. Notably, the review outlines a series of strategic approaches to mitigate the occurrence of “dead” metal during catalyst preparation, thus boosting the catalyst efficiency. The knowledge gathered is important for enhancing the preparation of catalysts, especially those containing precious metals. Beyond the practical implications for catalyst design, this study introduces a novel perspective for understanding and optimizing the catalyst performance. The insights are expected to broadly impact different scientific disciplines, empowered with heterogeneous catalysis and driving innovation in energy, environmental science, and materials chemistry, among others. Exploring the “dead” metal phenomenon and potential mitigation strategies brings the field closer to the ultimate goal of high-efficiency, low-cost catalysis.
Cite:
Mironenko R.M.
, Eremin D.B.
, Ananikov V.P.
The phenomenon of “dead” metal in heterogeneous catalysis: opportunities for increasing the efficiency of carbon-supported metal catalysts
Chemical Science. 2023. V.14. N48. P.14062-14073. DOI: 10.1039/D3SC04691E WOS Scopus РИНЦ OpenAlex
The phenomenon of “dead” metal in heterogeneous catalysis: opportunities for increasing the efficiency of carbon-supported metal catalysts
Chemical Science. 2023. V.14. N48. P.14062-14073. DOI: 10.1039/D3SC04691E WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Sep 5, 2023 |
| Accepted: | Oct 24, 2023 |
| Published online: | Nov 20, 2023 |
| Published print: | Dec 13, 2023 |
Identifiers:
| Web of science: | WOS:001104339400001 |
| Scopus: | 2-s2.0-85178318780 |
| Elibrary: | 64528644 |
| OpenAlex: | W4388825596 |