Abstract: Samples of Al-–Fe alloy of composition of (2.15±0.08) mass %, admixtures of not more than 0.2 mass %, were studied. It was demonstrated by XPA that the intermetallide of composition Al3.2Fe and polycrystalline aluminium were formed at alloying of metals. The interaction of Al-–Fe alloy samples with liquid Ga-–In eutectics was studied by scanning electron microscopy and energy-dispersive X-ray spectroscopy. It was found that Al-–Fe alloy became activated slower by liquid Ga-–In eutectics than polycrystalline aluminium and Al–-Ni alloys. The intermetallide phase of Al3.2Fe composition does not undergo significant chemical changes. It was demonstrated by multiple frustrated total internal reflection IR spectroscopy that aluminium chloride complexes of various compositions were in situ formed during the interaction of activated samples of Al-–Fe alloy with tert-butyl chloride. The complexes showed catalytic properties.

Cite: Arbuzov A.B. , Shilova A.V. , Trenikhin M.V. , Drozdov V.A.
Activation of Al-Fe Alloys by Liquid Ga-In Eutectics for the  in situ Formation of Catalytic Aluminium Chloride Complexes
Chemistry for Sustainable Development. 2017. V.25. N2. P.133-137. WOS РИНЦ

Original: Арбузов А.Б. , Шилова А.В. , Тренихин М.В. , Дроздов В.А.
Активирование сплавов Al-Fe жидкой эвтектикой Ga-In для формирования in situ каталитических алюмохлоридных комплексов
Химия в интересах устойчивого развития. 2017. Т.25. №2. С.135-139. DOI: 10.15372/KhUR20170203 РИНЦ OpenAlex

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Web of science:	WOS:000424486700003
Elibrary:	46561241

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