Activation of Al-Fe Alloys by Liquid Ga-In Eutectics for the in situ Formation of Catalytic Aluminium Chloride Complexes Научная публикация
Конференция |
V Всероссийская научная молодежная школа-конференция "Химия под знаком СИГМА: исследования, инновации, технологии" 15-20 мая 2016 , Омск |
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Журнал |
Chemistry for Sustainable Development
, E-ISSN: 1817-1818 |
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Вых. Данные | Год: 2017, Том: 25, Номер: 2, Страницы: 133-137 Страниц : 5 | ||||
Ключевые слова | Al-Fe alloy, Ga-In eutectic, activation, scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray phase analysis, IR spectroscopy, IR spectra of multiple frustrated total internal reflection (MFTIR), tert-butyl chloride, and catalytic aluminium chloride complexes | ||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Министерство науки и высшего образования Российской Федерации | 46.2.5 |
Реферат:
Samples of Al-Fe alloy of composition of (2.15±0.08) mass %, admixtures of not more than 0.2 mass %, were studied. It was demonstrated by XPA that the intermetallide of composition Al3.2Fe and polycrystalline aluminium were formed at alloying of metals. The interaction of Al-Fe alloy samples with liquid Ga-In eutectics was studied by scanning electron microscopy and energy-dispersive X-ray spectroscopy. It was found that Al-Fe alloy became activated slower by liquid Ga-In eutectics than polycrystalline aluminium and Al-Ni alloys. The intermetallide phase of Al3.2Fe composition does not undergo significant chemical changes. It was demonstrated by multiple frustrated total internal reflection IR spectroscopy that aluminium chloride complexes of various compositions were in situ formed during the interaction of activated samples of Al-Fe alloy with tert-butyl chloride. The complexes showed catalytic properties.
Библиографическая ссылка:
Arbuzov A.B.
, Shilova A.V.
, Trenikhin M.V.
, Drozdov V.A.
Activation of Al-Fe Alloys by Liquid Ga-In Eutectics for the in situ Formation of Catalytic Aluminium Chloride Complexes
Chemistry for Sustainable Development. 2017. V.25. N2. P.133-137. WOS РИНЦ
Activation of Al-Fe Alloys by Liquid Ga-In Eutectics for the in situ Formation of Catalytic Aluminium Chloride Complexes
Chemistry for Sustainable Development. 2017. V.25. N2. P.133-137. WOS РИНЦ
Оригинальная:
Арбузов А.Б.
, Шилова А.В.
, Тренихин М.В.
, Дроздов В.А.
Активирование сплавов Al-Fe жидкой эвтектикой Ga-In для формирования in situ каталитических алюмохлоридных комплексов
Химия в интересах устойчивого развития. 2017. Т.25. №2. С.135-139. DOI: 10.15372/KhUR20170203 РИНЦ OpenAlex
Активирование сплавов Al-Fe жидкой эвтектикой Ga-In для формирования in situ каталитических алюмохлоридных комплексов
Химия в интересах устойчивого развития. 2017. Т.25. №2. С.135-139. DOI: 10.15372/KhUR20170203 РИНЦ OpenAlex
Идентификаторы БД:
Web of science: | WOS:000424486700003 |
РИНЦ: | 46561241 |
Цитирование в БД:
БД | Цитирований |
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Web of science | 5 |