Solvent effect on the rate and direction of furfural transformations during hydrogenation over the Pd/C catalyst Full article
| Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 2022, Volume: 71, Number: 1, Pages: 64-69 Pages count : 6 DOI: 10.1007/s11172-022-3377-6 | ||||
| Tags | furfural, catalytic hydrogenation, palladium catalyst, solvent effect, furfuryl alcohol | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0004 |
Abstract:
The rate and directions of transformations during the liquid-phase hydrogenation of furfural with molecular hydrogen in the presence of the 5%Pd/C catalyst (at 423 K, 3 MPa) depend substantially on the chemical nature of the solvent. The main products of the catalytic transformations in alcohols are alkyl furyl ethers. Hydrogenation in solvent environment of aromatic hydrocarbons and 1,4-dioxane (nonpolar solvents), as well as in ethyl acetate and DMF (polar aprotic solvents) leads to the predominant formation of furfuryl alcohol, and its highest selectivity (up to 92%) is achieved with the use of DMF.
Cite:
Mironenko R.M.
, Belskaya O.B.
, Likholobov V.A.
Solvent effect on the rate and direction of furfural transformations during hydrogenation over the Pd/C catalyst
Russian Chemical Bulletin. 2022. V.71. N1. P.64-69. DOI: 10.1007/s11172-022-3377-6 WOS Scopus РИНЦ OpenAlex
Solvent effect on the rate and direction of furfural transformations during hydrogenation over the Pd/C catalyst
Russian Chemical Bulletin. 2022. V.71. N1. P.64-69. DOI: 10.1007/s11172-022-3377-6 WOS Scopus РИНЦ OpenAlex
Original:
Мироненко Р.М.
, Бельская О.Б.
, Лихолобов В.А.
Влияние растворителя на скорость и направления превращений фурфурола в ходе его гидрирования в присутствии катализатора Pd/C
Известия Академии наук. Серия химическая. 2022. №1. С.64-69. РИНЦ
Влияние растворителя на скорость и направления превращений фурфурола в ходе его гидрирования в присутствии катализатора Pd/C
Известия Академии наук. Серия химическая. 2022. №1. С.64-69. РИНЦ
Dates:
| Submitted: | May 24, 2021 |
| Accepted: | Jun 28, 2021 |
| Published print: | Feb 14, 2022 |
| Published online: | Feb 14, 2022 |
Identifiers:
| Web of science: | WOS:000755136000008 |
| Scopus: | 2-s2.0-85124954796 |
| Elibrary: | 8181932 |
| OpenAlex: | W4213062269 |