The unique chemistry of 4,5-dichloro-2-dichloromethylene-4-cyclopentene-1,3-dione and thiourea

The unique chemistry of 4,5-dichloro-2-dichloromethylene-4-cyclopentene-1,3-dione and thiourea Full article

Conference

VI Всероссийская научная молодежная школа-конференция «Химия под знаком СИГМА: исследования, инновации, технологии"
18-20 May 2020 , Омск

Journal

AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616

Output data

Year: 2020, Volume: 2301, Article number : 040019, Pages count : 6 DOI: 10.1063/5.0032826

Authors

Talsi V.P. ¹ , Yurpalov V.L. ¹

Affiliations

1	Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

V. 47

The information on the structure of the telomer that was produced by the reaction of thiourea with 4,5-dichloro-2-dichloromethylene-4-cyclopentene-1,3-dione have been refined. Mixing of acetone solutions of 4,5-dichloro2-dichloromethylene-4-cyclopentene-1,3-dione and thiourea leads to immediate and quantitative formation of the telomer precipitate, which is a Möbius aromatic compound in which half of carbon atoms are simultaneously in saturated and unsaturated state due to the involvement of electron-deficient six-electron four-centered (6e – 4c) ı-bonds.

Talsi V.P. , Yurpalov V.L.
The unique chemistry of 4,5-dichloro-2-dichloromethylene-4-cyclopentene-1,3-dione and thiourea
AIP Conference Proceedings. 2020. V.2301. 040019 :1-6. DOI: 10.1063/5.0032826 Scopus РИНЦ OpenAlex

Published online:

Dec 8, 2020

Scopus:	2-s2.0-85098083283
Elibrary:	45063767
OpenAlex:	W3110678228

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