The unique chemistry of 4,5-dichloro-2-dichloromethylene-4-cyclopentene-1,3-dione and thiourea

The unique chemistry of 4,5-dichloro-2-dichloromethylene-4-cyclopentene-1,3-dione and thiourea Научная публикация

Конференция

VI Всероссийская научная молодежная школа-конференция «Химия под знаком СИГМА: исследования, инновации, технологии"
18-20 мая 2020 , Омск

Журнал

AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616

Вых. Данные

Год: 2020, Том: 2301, Номер статьи : 040019, Страниц : 6 DOI: 10.1063/5.0032826

Авторы

Talsi V.P. ¹ , Yurpalov V.L. ¹

Организации

1	Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis

Информация о финансировании (1)

Министерство науки и высшего образования Российской Федерации

V. 47

The information on the structure of the telomer that was produced by the reaction of thiourea with 4,5-dichloro-2-dichloromethylene-4-cyclopentene-1,3-dione have been refined. Mixing of acetone solutions of 4,5-dichloro2-dichloromethylene-4-cyclopentene-1,3-dione and thiourea leads to immediate and quantitative formation of the telomer precipitate, which is a Möbius aromatic compound in which half of carbon atoms are simultaneously in saturated and unsaturated state due to the involvement of electron-deficient six-electron four-centered (6e – 4c) ı-bonds.

Talsi V.P. , Yurpalov V.L.
The unique chemistry of 4,5-dichloro-2-dichloromethylene-4-cyclopentene-1,3-dione and thiourea
AIP Conference Proceedings. 2020. V.2301. 040019 :1-6. DOI: 10.1063/5.0032826 Scopus РИНЦ OpenAlex

Опубликована online:

8 дек. 2020 г.

Scopus:	2-s2.0-85098083283
РИНЦ:	45063767
OpenAlex:	W3110678228

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