Conversion of methane and C5-hydrocarbons over platinum-alumina catalyst under non-oxidative conditions

Conversion of methane and C5-hydrocarbons over platinum-alumina catalyst under non-oxidative conditions Full article

Conference

VI Всероссийская научная молодежная школа-конференция «Химия под знаком СИГМА: исследования, инновации, технологии"
18-20 May 2020 , Омск

Journal

AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616

Output data

Year: 2020, Volume: 2301, Article number : 030008, Pages count : 7 DOI: 10.1063/5.0032863

Authors

Kazakova O.A. ¹ , Vinichenko N.V. ¹ , Fedorov A.E. ¹ , Belyi A.S. ¹

Affiliations

1	Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

46.2.4

The platinum-alumina catalyst with platinum content of 0.5 wt.% was synthesized and investigated in the coconversion of methane with pentane and pent-1-ene to aromatic hydrocarbons (benzene and toluene) under non-oxidative conditions. The catalyst was characterized by atomic emission analysis, IR-spectroscopy, CO chemisorption. There are both metallic platinum and its ionic forms on the platinum-alumina catalyst surface, platinum dispersion is 68 %. Basic directions of non-oxidative co-conversion of methane and model C5-hydrocarbons were determined in the temperature range 748–823 K. The pent-1-ene isomers and diene hydrocarbons were detected and determined in the mixtures of products of co-conversion of methane and pent-1-ene. The yield of benzene and toluene at 823 K is 35 wt.% for coconversion of methane and pent-1-ene which is 13 wt.% more than for the co-conversion of methane with pentane at the same temperature.

Kazakova O.A. , Vinichenko N.V. , Fedorov A.E. , Belyi A.S.
Conversion of methane and C5-hydrocarbons over platinum-alumina catalyst under non-oxidative conditions
AIP Conference Proceedings. 2020. V.2301. 030008 :1-7. DOI: 10.1063/5.0032863 Scopus РИНЦ OpenAlex

Published online:

Dec 8, 2020

Scopus:	2-s2.0-85098063965
Elibrary:	45058259
OpenAlex:	W3112914049

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