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Conversion of methane and C5-hydrocarbons over platinum-alumina catalyst under non-oxidative conditions Научная публикация

Конференция VI Всероссийская научная молодежная школа-конференция «Химия под знаком СИГМА: исследования, инновации, технологии"
18-20 мая 2020 , Омск
Журнал AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616
Вых. Данные Год: 2020, Том: 2301, Номер статьи : 030008, Страниц : 7 DOI: 10.1063/5.0032863
Авторы Kazakova O.A. 1 , Vinichenko N.V. 1 , Fedorov A.E. 1 , Belyi A.S. 1
Организации
1 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis

Информация о финансировании (1)

1 Министерство науки и высшего образования Российской Федерации 46.2.4

Реферат: The platinum-alumina catalyst with platinum content of 0.5 wt.% was synthesized and investigated in the coconversion of methane with pentane and pent-1-ene to aromatic hydrocarbons (benzene and toluene) under non-oxidative conditions. The catalyst was characterized by atomic emission analysis, IR-spectroscopy, CO chemisorption. There are both metallic platinum and its ionic forms on the platinum-alumina catalyst surface, platinum dispersion is 68 %. Basic directions of non-oxidative co-conversion of methane and model C5-hydrocarbons were determined in the temperature range 748–823 K. The pent-1-ene isomers and diene hydrocarbons were detected and determined in the mixtures of products of co-conversion of methane and pent-1-ene. The yield of benzene and toluene at 823 K is 35 wt.% for coconversion of methane and pent-1-ene which is 13 wt.% more than for the co-conversion of methane with pentane at the same temperature.
Библиографическая ссылка: Kazakova O.A. , Vinichenko N.V. , Fedorov A.E. , Belyi A.S.
Conversion of methane and C5-hydrocarbons over platinum-alumina catalyst under non-oxidative conditions
AIP Conference Proceedings. 2020. V.2301. 030008 :1-7. DOI: 10.1063/5.0032863 Scopus РИНЦ OpenAlex
Даты:
Опубликована online: 8 дек. 2020 г.
Идентификаторы БД:
Scopus: 2-s2.0-85098063965
РИНЦ: 45058259
OpenAlex: W3112914049
Цитирование в БД: Пока нет цитирований
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