Palladium Nanoparticles Supported on Carbon Nanoglobules as Efficient Catalysts for Obtaining Benzocaine via Selective Hydrogenation of Ethyl 4-Nitrobenzoate

Palladium Nanoparticles Supported on Carbon Nanoglobules as Efficient Catalysts for Obtaining Benzocaine via Selective Hydrogenation of Ethyl 4-Nitrobenzoate Full article

Journal

Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905

Output data

Year: 2018, Volume: 114, Pages: 46-50 Pages count : 5 DOI: 10.1016/j.catcom.2018.06.002

Tags

Catalytic hydrogenation; Carbon nanoglobules; Palladium catalysts; Ethyl 4-nitrobenzoate; Benzocaine

Authors

Mironenko Roman M. ^1,2 , Belskaya Olga B. ^1,3 , Gulyaeva Tatiana I. ¹ , Trenikhin Mikhail V. ^1,3 , Likholobov Vladimir A. ^1,4

Affiliations

1	Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences
2	Dostoevsky Omsk State University
3	Omsk State Technical University
4	Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences

Funding (1)

Russian Foundation for Basic Research

16-29-10742

The palladium catalysts prepared using carbon nanoglobules (CNGs) as the support and containing no more than 2 wt% Pd were shown to be highly effective for the liquid-phase hydrogenation of ethyl 4-nitrobenzoate under mild conditions. Regardless of the kind of CNGs and the catalyst preparation method, the most of the Pd/CNGs catalysts allow achieving a complete conversion of substrate giving benzocaine in a 100% yield. The Pd/CNGs catalyst is easily recycled many times without loss of its catalytic performance. The results obtained may be useful for the development of effective Pd/C catalysts for chemoselective hydrogenation of various nitroarenes.

Mironenko R.M. , Belskaya O.B. , Gulyaeva T.I. , Trenikhin M.V. , Likholobov V.A.
Palladium Nanoparticles Supported on Carbon Nanoglobules as Efficient Catalysts for Obtaining Benzocaine via Selective Hydrogenation of Ethyl 4-Nitrobenzoate
Catalysis Communications. 2018. V.114. P.46-50. DOI: 10.1016/j.catcom.2018.06.002 WOS Scopus РИНЦ OpenAlex

Submitted:	Apr 27, 2018
Accepted:	Jun 1, 2018
Published online:	Jun 6, 2018
Published print:	Aug 1, 2018

Web of science:	WOS:000440771300011
Scopus:	2-s2.0-85048274044
Elibrary:	35668721
OpenAlex:	W2805662461

DB	Citing
Web of science	13
Scopus	16
Elibrary	5
OpenAlex	16