A Study of Intermolecular Hydrogen Transfer from Naphthenes to 1-Hexene over Zeolite Catalysts Full article
| Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Output data | Year: 2016, Volume: 516, Pages: 153-159 Pages count : 7 DOI: 10.1016/j.apcata.2016.02.028 | ||
| Tags | Intermolecular hydrogen transfer Deuterium Naphthene Olefin Zeolite catalyst | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | V.46.2.8 |
Abstract:
The mechanism of hydrogen transfers from naphthenes (methylcyclohexane, cyclohexane) or their deuterated derivatives to 1-hexene was specified over model acid zeolite catalysts (HREY or HZSM5). The composition of products is determined by two reactions-cracking and intermolecular hydrogen transfer. The monomolecular cracking reaction proceeds mostly on HZSM-5 zeolite, whereas the bimolecular hydrogen transfer reactions are catalyzed by the wide-pore HREY zeolite. It was found that during the hydrogen transfer from the naphthene molecule (hydrogen donor) to the olefin molecule (hydrogen acceptor) only one hydrogen atom is transferred, whereas the second hydrogen atom comes from the Brønsted acid site of the catalyst
Cite:
Potapenko O.V.
, Doronin V.P.
, Sorokina T.P.
, Krol O.V.
, Likholobov V.A.
A Study of Intermolecular Hydrogen Transfer from Naphthenes to 1-Hexene over Zeolite Catalysts
Applied Catalysis A: General. 2016. V.516. P.153-159. DOI: 10.1016/j.apcata.2016.02.028 WOS Scopus РИНЦ OpenAlex
A Study of Intermolecular Hydrogen Transfer from Naphthenes to 1-Hexene over Zeolite Catalysts
Applied Catalysis A: General. 2016. V.516. P.153-159. DOI: 10.1016/j.apcata.2016.02.028 WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Nov 2, 2015 |
| Accepted: | Feb 25, 2016 |
| Published online: | Feb 28, 2016 |
| Published print: | Apr 24, 2016 |
Identifiers:
| Web of science: | WOS:000374717000017 |
| Scopus: | 2-s2.0-84959563371 |
| Elibrary: | 26982592 |
| OpenAlex: | W2286938214 |