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A Study of Intermolecular Hydrogen Transfer from Naphthenes to 1-Hexene over Zeolite Catalysts Научная публикация

Журнал Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875
Вых. Данные Год: 2016, Том: 516, Страницы: 153-159 Страниц : 7 DOI: 10.1016/j.apcata.2016.02.028
Ключевые слова Intermolecular hydrogen transfer Deuterium Naphthene Olefin Zeolite catalyst
Авторы Potapenko O.V. 1 , Doronin V.P. 1 , Sorokina T.P. 1 , Krol O.V. 1 , Likholobov V.A. 1
Организации
1 Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences, Russian Federation

Информация о финансировании (1)

1 Федеральное агентство научных организаций V.46.2.8

Реферат: The mechanism of hydrogen transfers from naphthenes (methylcyclohexane, cyclohexane) or their deuterated derivatives to 1-hexene was specified over model acid zeolite catalysts (HREY or HZSM5). The composition of products is determined by two reactions-cracking and intermolecular hydrogen transfer. The monomolecular cracking reaction proceeds mostly on HZSM-5 zeolite, whereas the bimolecular hydrogen transfer reactions are catalyzed by the wide-pore HREY zeolite. It was found that during the hydrogen transfer from the naphthene molecule (hydrogen donor) to the olefin molecule (hydrogen acceptor) only one hydrogen atom is transferred, whereas the second hydrogen atom comes from the Brønsted acid site of the catalyst
Библиографическая ссылка: Potapenko O.V. , Doronin V.P. , Sorokina T.P. , Krol O.V. , Likholobov V.A.
A Study of Intermolecular Hydrogen Transfer from Naphthenes to 1-Hexene over Zeolite Catalysts
Applied Catalysis A: General. 2016. V.516. P.153-159. DOI: 10.1016/j.apcata.2016.02.028 WOS Scopus РИНЦ OpenAlex
Даты:
Поступила в редакцию: 2 нояб. 2015 г.
Принята к публикации: 25 февр. 2016 г.
Опубликована online: 28 февр. 2016 г.
Опубликована в печати: 24 апр. 2016 г.
Идентификаторы БД:
Web of science: WOS:000374717000017
Scopus: 2-s2.0-84959563371
РИНЦ: 26982592
OpenAlex: W2286938214
Цитирование в БД:
БД Цитирований
Web of science 16
Scopus 19
РИНЦ 8
OpenAlex 22
Альметрики: