Comparative Study of Rubidium and Cesium as Promoters in Carbon-supported Ruthenium Catalysts for Ammonia Synthesis Full article
| Journal |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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| Output data | Year: 2008, Volume: 120, Number: 3-4, Pages: 204-209 Pages count : 6 DOI: 10.1007/s10562-007-9270-y | ||||||
| Tags | Ammonia synthesis, Cs, Promoter-support interaction, Rb, Ruthenium catalysts, TEM, XPS | ||||||
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Abstract:
Sibunit-supported Ru-catalysts promoted with cesium or rubidium compounds have been comparatively
studied with XPS. The cesium promoter interacts both with support and with active component. The absence of the promoter–support interaction in the case of rubidium provides a stronger interaction between promoter and active component compared to the cesium-based catalysts. These differences in the promoter–support and promoter–metal interactions are exhibited when a sequence of ruthenium and alkali introduction are changed.
Cite:
Larichev Y.V.
, Shlyapin D.A.
, Tsyrulʹnikov P.G.
, Bukhtiyarov V.I.
Comparative Study of Rubidium and Cesium as Promoters in Carbon-supported Ruthenium Catalysts for Ammonia Synthesis
Catalysis Letters. 2008. V.120. N3-4. P.204-209. DOI: 10.1007/s10562-007-9270-y WOS Scopus РИНЦ OpenAlex ANCAN
Comparative Study of Rubidium and Cesium as Promoters in Carbon-supported Ruthenium Catalysts for Ammonia Synthesis
Catalysis Letters. 2008. V.120. N3-4. P.204-209. DOI: 10.1007/s10562-007-9270-y WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | May 3, 2007 |
| Accepted: | Sep 4, 2007 |
| Published online: | Sep 18, 2007 |
| Published print: | Dec 31, 2007 |
Identifiers:
| ≡ Web of science: | WOS:000252252400007 |
| ≡ Scopus: | 2-s2.0-38049188225 |
| ≡ Elibrary: | 13594078 |
| ≡ OpenAlex: | W2037543536 |
| ≡ Chemical Abstracts: | 2008:52648 |
| ≡ Chemical Abstracts (print): | 148:222944 |