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Comparative Study of Rubidium and Cesium as Promoters in Carbon-supported Ruthenium Catalysts for Ammonia Synthesis Научная публикация

Журнал Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X
Вых. Данные Год: 2008, Том: 120, Номер: 3-4, Страницы: 204-209 Страниц : 6 DOI: 10.1007/s10562-007-9270-y
Ключевые слова Ammonia synthesis, Cs, Promoter-support interaction, Rb, Ruthenium catalysts, TEM, XPS
Авторы Larichev Yu.V. 1 , Shlyapin D.A. 2 , Tsyrulʹnikov P.G. 2 , Bukhtiyarov V.I. 1,3
Организации
1 Boreskov Institute of Catalysis, Novosibirsk 630090, Russia
2 Institute of Hydrocarbons Processing, Omsk 644040, Russia
3 Novosibirsk State University, Novosibirsk 630090, Russia

Реферат: Sibunit-supported Ru-catalysts promoted with cesium or rubidium compounds have been comparatively studied with XPS. The cesium promoter interacts both with support and with active component. The absence of the promoter–support interaction in the case of rubidium provides a stronger interaction between promoter and active component compared to the cesium-based catalysts. These differences in the promoter–support and promoter–metal interactions are exhibited when a sequence of ruthenium and alkali introduction are changed.
Библиографическая ссылка: Larichev Y.V. , Shlyapin D.A. , Tsyrulʹnikov P.G. , Bukhtiyarov V.I.
Comparative Study of Rubidium and Cesium as Promoters in Carbon-supported Ruthenium Catalysts for Ammonia Synthesis
Catalysis Letters. 2008. V.120. N3-4. P.204-209. DOI: 10.1007/s10562-007-9270-y WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
Поступила в редакцию: 3 мая 2007 г.
Принята к публикации: 4 сент. 2007 г.
Опубликована online: 18 сент. 2007 г.
Опубликована в печати: 31 дек. 2007 г.
Идентификаторы БД:
≡ Web of science: WOS:000252252400007
≡ Scopus: 2-s2.0-38049188225
≡ РИНЦ: 13594078
≡ OpenAlex: W2037543536
≡ Chemical Abstracts: 2008:52648
≡ Chemical Abstracts (print): 148:222944
Альметрики: