The surface study of the Pd-Ga/Sibunit catalysts for acetylene hydrogenation | Sciact

The surface study of the Pd-Ga/Sibunit catalysts for acetylene hydrogenation Научная публикация

Конференция

9-ая международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства"
26-28 февр. 2019 , Омск

Журнал

AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616

Вых. Данные

Год: 2019, Том: 2141, Номер статьи : 020019, Страниц : 7 DOI: 10.1063/1.5122038

Авторы

Glyzdova D.V. ¹ , Afonasenko T.N. ¹ , Domanina T.P. ¹ , Leont’eva N.N. ¹ , Tsapina A.M. ² , Saraev A.A. ² , Shlyapin D.A. ¹

Организации

1	Center of New Chemical Technologies of the Federal Research Center Boreskov Institute of Catalysis SB RAS
2	Federal Research Center Boreskov Institute of Catalysis

Информация о финансировании (1)

Министерство науки и высшего образования Российской Федерации

46.2.5

Structural, electronic and catalytic properties of Pd-Ga/Sibunit and Pd/Sibunit catalysts are studied by XRD and XPS methods. Using XRD, it was shown that the bimetallic Pd2+xGa1–x phase is formed in the model 7%Pd-4.62%Ga/Sibunit sample after reduction in H2 at 500 °C. XPS analysis of the samples under conditions of gradual heating in H2 showed that gallium and palladium that are located on the catalyst surface are present mainly in the oxidized state and a small amount as a mixed palladium-gallium phase. However, the introduction of gallium significantly increases the dispersion of catalytic active particles, which is likely the reason for the higher catalytic activity of Pd-Ga/Sibunit in acetylene hydrogenation but lower selectivity towards ethylene compared with the monometallic sample.

Glyzdova D.V. , Afonasenko T.N. , Domanina T.P. , Leont’eva N.N. , Tsapina A.M. , Saraev A.A. , Shlyapin D.A.
The surface study of the Pd-Ga/Sibunit catalysts for acetylene hydrogenation
AIP Conference Proceedings. 2019. V.2141. 020019 :1-7. DOI: 10.1063/1.5122038 WOS Scopus РИНЦ OpenAlex

Опубликована online:

28 авг. 2019 г.

Web of science:	WOS:000516716100019
Scopus:	2-s2.0-85072102751
РИНЦ:	41645381
OpenAlex:	W2970066865

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