The composition of transformation products of 2,4,6‐trinitrobenzoic acid in the aqueous‐phase hydrogenation over Pd/C catalysts Full article
| Journal |
Magnetic Resonance in Chemistry
ISSN: 0749-1581 , E-ISSN: 1097-458X |
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| Output data | Year: 2020, Volume: 58, Number: 1, Pages: 84-96 Pages count : 13 DOI: 10.1002/mrc.4931 | ||||
| Tags | 1H and 13C NMR spectroscopy, aqueous‐phase reaction, catalytic hydrogenation, palladium catalyst, trinitrobenzoic acid | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 16-03-00601-a |
Abstract:
Due to a detailed analysis of NMR spectra of the reaction solutions with different composition obtained by the aqueous‐phase catalytic (Pd/C) hydrogenation of 2,4,6‐trinitrobenzoic acid, the intermediate compounds were identified and a more substantiated mechanism was proposed for the formation of main reaction products – 1,3,5‐triaminobenzene and cyclohexane‐1,3,5‐trione trioxime. Condensation of the 1,3,5‐triaminobenzene molecules produced by complete hydrogenation of 2,4,6‐trinitrobenzoic acid was shown to result in the formation of a paramagnetic heterocyclic compound.
Cite:
Talsi V.P.
, Belskaya O.B.
, Yurpalov V.L.
The composition of transformation products of 2,4,6‐trinitrobenzoic acid in the aqueous‐phase hydrogenation over Pd/C catalysts
Magnetic Resonance in Chemistry. 2020. V.58. N1. P.84-96. DOI: 10.1002/mrc.4931 WOS Scopus РИНЦ OpenAlex
The composition of transformation products of 2,4,6‐trinitrobenzoic acid in the aqueous‐phase hydrogenation over Pd/C catalysts
Magnetic Resonance in Chemistry. 2020. V.58. N1. P.84-96. DOI: 10.1002/mrc.4931 WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | May 8, 2019 |
| Accepted: | Jul 24, 2019 |
| Published online: | Jul 30, 2019 |
| Published print: | Dec 29, 2019 |
Identifiers:
| Web of science: | WOS:000481454200001 |
| Scopus: | 2-s2.0-85070747661 |
| Elibrary: | 43207006 |
| OpenAlex: | W2966063862 |