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The composition of transformation products of 2,4,6‐trinitrobenzoic acid in the aqueous‐phase hydrogenation over Pd/C catalysts Научная публикация

Журнал Magnetic Resonance in Chemistry
ISSN: 0749-1581 , E-ISSN: 1097-458X
Вых. Данные Год: 2020, Том: 58, Номер: 1, Страницы: 84-96 Страниц : 13 DOI: 10.1002/mrc.4931
Ключевые слова 1H and 13C NMR spectroscopy, aqueous‐phase reaction, catalytic hydrogenation, palladium catalyst, trinitrobenzoic acid
Авторы Talsi Valentin P. 1 , Belskaya Olga B. 1,2 , Yurpalov Vyacheslav L. 1
Организации
1 Center of New Chemical Technologies of the Federal Research Center Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Omsk, Russia
2 Department of Chemical Technology, Omsk State Technical University, Omsk, Russia

Информация о финансировании (1)

1 Российский фонд фундаментальных исследований 16-03-00601-a

Реферат: Due to a detailed analysis of NMR spectra of the reaction solutions with different composition obtained by the aqueous‐phase catalytic (Pd/C) hydrogenation of 2,4,6‐trinitrobenzoic acid, the intermediate compounds were identified and a more substantiated mechanism was proposed for the formation of main reaction products – 1,3,5‐triaminobenzene and cyclohexane‐1,3,5‐trione trioxime. Condensation of the 1,3,5‐triaminobenzene molecules produced by complete hydrogenation of 2,4,6‐trinitrobenzoic acid was shown to result in the formation of a paramagnetic heterocyclic compound.
Библиографическая ссылка: Talsi V.P. , Belskaya O.B. , Yurpalov V.L.
The composition of transformation products of 2,4,6‐trinitrobenzoic acid in the aqueous‐phase hydrogenation over Pd/C catalysts
Magnetic Resonance in Chemistry. 2020. V.58. N1. P.84-96. DOI: 10.1002/mrc.4931 WOS Scopus РИНЦ OpenAlex
Даты:
Поступила в редакцию: 8 мая 2019 г.
Принята к публикации: 24 июл. 2019 г.
Опубликована online: 30 июл. 2019 г.
Опубликована в печати: 29 дек. 2019 г.
Идентификаторы БД:
Web of science: WOS:000481454200001
Scopus: 2-s2.0-85070747661
РИНЦ: 43207006
OpenAlex: W2966063862
Цитирование в БД:
БД Цитирований
Scopus 3
Web of science 4
OpenAlex 7
Альметрики: