Nitration of 1,3,3-trimethyl-1-phenylindane on mesoporous aluminosilicates Научная публикация
Журнал |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Вых. Данные | Год: 2015, Том: 64, Номер: 4, Страницы: 852-858 Страниц : 7 DOI: 10.1007/s11172-015-0944-0 | ||||||
Ключевые слова | nitration of 1,3,3-trimethyl-1-phenylindane; nitrophenylindane; dinitrophenylindane; mesoporous aluminosilicates | ||||||
Авторы |
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Организации |
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Реферат:
Nitration of 1,3,3-trimethyl-1-phenylindane (phenylindane) by nitric acid of different concentration over mesoporous aluminosilicates with the molar ratios SiO2 : Al2O3 = 20, 40, and 80 was studied. The effects of the SiO2 : Al2O3 and phenylindane : nitric acid ratios, the concentration of nitric acid, and temperature on the conversion of phenylindane and the yield of dinitrophenylindane were revealed. The aluminosilicate samples with a SiO2 : Al2O3 ratio of 20 are shown to have the highest activity. In the presence of these samples, the conversion of phenylindane reaches 100% with a selectivity of formation of 5and 6-nitro-1-(4A '-nitrophenyl)1,3,3-trimethylindanes close to 80% (70% nitric acid, 100 degrees C).
Библиографическая ссылка:
Grigorieva N.G.
, Agliullin M.R.
, Talzi V.P.
, Vodyankina O.V.
, Kutepov B.I.
Nitration of 1,3,3-trimethyl-1-phenylindane on mesoporous aluminosilicates
Russian Chemical Bulletin. 2015. V.64. N4. P.852-858. DOI: 10.1007/s11172-015-0944-0 WOS Scopus РИНЦ
Nitration of 1,3,3-trimethyl-1-phenylindane on mesoporous aluminosilicates
Russian Chemical Bulletin. 2015. V.64. N4. P.852-858. DOI: 10.1007/s11172-015-0944-0 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 21 июл. 2014 г. |
Опубликована в печати: | 1 апр. 2015 г. |
Опубликована online: | 16 дек. 2015 г. |
Идентификаторы БД:
Web of science | WOS:000366640400015 |
Scopus | 2-s2.0-84950107447 |
РИНЦ | 26795501 |
OpenAlex | W2280259889 |