CO Oxidation over Pd/MeOx/M Catalysts, where MeOx/M Carrier is Prepared by Plasma Spraying (MeOx: Al2O3, Al2O3-CeO2, Al2O3-MnO2; M: Ni-Al/Stainless Steel)

CO Oxidation over Pd/MeOx/M Catalysts, where MeOx/M Carrier is Prepared by Plasma Spraying (MeOx: Al2O3, Al2O3-CeO2, Al2O3-MnO2; M: Ni-Al/Stainless Steel) Full article

Conference

V Всероссийская научная молодежная школа-конференция "Химия под знаком СИГМА: исследования, инновации, технологии"
15-20 May 2016 , Омск

Journal

Chemistry for Sustainable Development
, E-ISSN: 1817-1818

Output data

Year: 2017, Volume: 25, Number: 2, Pages: 145-152 Pages count : 8

Tags

CO oxidation; catalysts; Al2O3; Al2O3-CeO2; Al2O3-MnO2; plasma application; [Pd(NH3)(4)](NO3)(2); scanning electron microscopy (SEM); X-ray phase analysis

Authors

Borisov V.A. ^1,2 , Sigaeva S.S. ^1,3 , Suprunov G.I. ⁴ , Anoshkina E.A. ¹ , Temerev V.L. ¹ , Ivanov A.L. ⁵ , Tsyrul'nikov P.G. ¹

Affiliations

1	Russian Acad Sci, Siberian Branch, Inst Hydrocarbons Proc, Omsk, Russia
2	Omsk State Tech Univ, Omsk, Russia
3	Dostoevsky Omsk State University, Omsk, Russia
4	JSC Omsk Res Inst Technol & Org Engine Prod, Omsk, Russia
5	Siberian State Automobile & Highway Univ, Omsk, Russia

The activity in the CO oxidation reaction of MeOx/M and Pd/MeOx/Ni-Al/stainless steel (SS) catalysts where MeOx: Al2O3, Al2O3-CeO2, Al2O3-MnO2 carrier is applied to Ni-Al/SS (grids made of SS with an evaporated Ni-Al layer) was studied. Samples, in which grids made from fechral and nichrome were used, were prepared for comparison. It was demonstrated that intermediate Ni-Al coating itself serving to increase adhesion of oxides to a metal substrate exhibited the catalytic activity. The most active samples activated and not activated by palladium were determined according to the results of catalytic trials. All catalysts were characterized by X-ray phase analysis, scanning electron microscopy methods. The most active Pd/Al2O3/Ni Al/SS sample was additionally studied by scanning electron microscopy (SEM) with local analysis.

Borisov V.A. , Sigaeva S.S. , Suprunov G.I. , Anoshkina E.A. , Temerev V.L. , Ivanov A.L. , Tsyrul'nikov P.G.
CO Oxidation over Pd/MeOx/M Catalysts, where MeOx/M Carrier is Prepared by Plasma Spraying (MeOx: Al2O3, Al2O3-CeO2, Al2O3-MnO2; M: Ni-Al/Stainless Steel)
Chemistry for Sustainable Development. 2017. V.25. N2. P.145-152. WOS РИНЦ

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