Performance of a zeolite-containing catalyst and catalysts based on noble metals in intermolecular hydrogen transfer between С6 hydrocarbons Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2017, Volume: 58, Number: 3, Pages: 271-278 Pages count : 8 DOI: 10.1134/S002315841703003X | ||
Tags | cyclohexene; deuterium; intermolecular hydrogen transfer; Pd; Pt; zeolite-containing catalyst | ||
Authors |
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Affiliations |
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Funding (2)
1 | Ministry of Science and Higher Education of the Russian Federation | 46.2.4 |
2 | Ministry of Science and Higher Education of the Russian Federation | 14.607.21.0111 |
Abstract:
The activities of a zeolite-containing catalyst and catalysts containing a noble metal in intermolecular hydrogen transfer between С6 hydrocarbons are compared. The zeolite-containing catalyst is ineffective in hydrogen transfer from cyclohexane to 1-hexene and in cyclohexene conversion at <400°С. Cyclohexene disproportionation at Т < 200°С takes place only over catalysts containing a noble metal. The cyclohexene conversion selectivity depends strongly on the support type. Using deuterated compounds, it has been demonstrated that intermolecular hydrogen transfer via the dehydrogenation–hydrogenation mechanism involves only the initial cyclohexene. © 2017, Pleiades Publishing, Ltd.
Cite:
Bukin K.A.
, Potapenko O.V.
, Doronin V.P.
, Sorokina T.P.
, Gulyaeva T.I.
Performance of a zeolite-containing catalyst and catalysts based on noble metals in intermolecular hydrogen transfer between С6 hydrocarbons
Kinetics and Catalysis. 2017. V.58. N3. P.271-278. DOI: 10.1134/S002315841703003X WOS Scopus РИНЦ OpenAlex
Performance of a zeolite-containing catalyst and catalysts based on noble metals in intermolecular hydrogen transfer between С6 hydrocarbons
Kinetics and Catalysis. 2017. V.58. N3. P.271-278. DOI: 10.1134/S002315841703003X WOS Scopus РИНЦ OpenAlex
Original:
Букин К.А.
, Потапенко О.В.
, Доронин В.П.
, Сорокина Т.П.
, Гуляева Т.И.
Исследование цеолитсодержащего катализатора и катализаторов на основе благородных металлов в реакциях межмолекулярного переноса водорода между С6-углеводородами
Кинетика и катализ. 2017. Т.58. №3. С.283-291. DOI: 10.7868/s0453881117030042 РИНЦ OpenAlex
Исследование цеолитсодержащего катализатора и катализаторов на основе благородных металлов в реакциях межмолекулярного переноса водорода между С6-углеводородами
Кинетика и катализ. 2017. Т.58. №3. С.283-291. DOI: 10.7868/s0453881117030042 РИНЦ OpenAlex
Dates:
Published print: | May 1, 2017 |
Published online: | Jul 19, 2017 |
Identifiers:
Web of science: | WOS:000405959400006 |
Scopus: | 2-s2.0-85025096452 |
Elibrary: | 31058747 |
OpenAlex: | W2737820560 |