Synthesis and Study of Nanodispersed Carbon in the Combustion of Acetylene in a Flow Detonation Tube Full article
Journal |
Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296 |
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Output data | Year: 2018, Volume: 91, Number: 12, Pages: 2003-2011 Pages count : 9 DOI: 10.1134/S1070427218120121 | ||||
Tags | Nanodispersed carbon, acetylene–oxygen mixtures, detonation combustion and decomposition, Raman spectroscopy, X-ray diffraction analysis, high-resolution transmission electron microscopy, bulk electrical resistance | ||||
Authors |
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Affiliations |
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Funding (1)
1 | Ministry of Science and Higher Education of the Russian Federation | V.45.2.8 |
Abstract:
Nanodispersed carbon was obtained via high-temperature combustion of acetylene–oxygen mixtures in a flow-through tubular chamber in cyclic detonation waves (“pulsed detonation”) at a constant propagation velocity (D det ≈ 2150 m s –1 ). It was found that the position of a plateau in the curve describing how the detonation velocity depends on the content of oxygen in the starting detonation mixture in the range 15–30% coincides with the range of descending branches of the dependences of the specific adsorption surface area and adsorption of dibutyl phthalate by aggregated particles. Various physicochemical methods of analysis (X-ray diffraction analysis, Raman spectroscopy, high-resolution transmission electron microscopy, etc.) were used to comparatively examine the properties of nanodispersed carbon and of the known industrially produced domestic and foreign brands of technical-grade carbon. The conditions were found in which detonation nanocarbon particles are obtained in a certain range of parameters of micro- and macrostructures with improved morphology and basic electrical properties. © 2018, Pleiades Publishing, Ltd.
Cite:
Shaitanov A.G.
, Surovikin Y.V.
, Rezanov I.V.
, Shtertser A.A.
, Ul’yanitskii V.Y.
, Vasil’ev A.A.
, Likholobov V.A.
Synthesis and Study of Nanodispersed Carbon in the Combustion of Acetylene in a Flow Detonation Tube
Russian Journal of Applied Chemistry. 2018. V.91. N12. P.2003-2011. DOI: 10.1134/S1070427218120121 WOS Scopus РИНЦ OpenAlex
Synthesis and Study of Nanodispersed Carbon in the Combustion of Acetylene in a Flow Detonation Tube
Russian Journal of Applied Chemistry. 2018. V.91. N12. P.2003-2011. DOI: 10.1134/S1070427218120121 WOS Scopus РИНЦ OpenAlex
Original:
Шайтанов А.Г.
, Суровикин Ю.В.
, Резанов И.В.
, Штерцер А.А.
, Ульяницкий В.Ю.
, Васильев А.А.
, Лихолобов В.А.
Получение и исследование нанодисперсного углерода при сжигании ацетилена в проточной детонационной трубе
Журнал прикладной химии. 2018. Т.91. №12. С.1751-1759. DOI: 10.1134/S0044461818120095 РИНЦ
Получение и исследование нанодисперсного углерода при сжигании ацетилена в проточной детонационной трубе
Журнал прикладной химии. 2018. Т.91. №12. С.1751-1759. DOI: 10.1134/S0044461818120095 РИНЦ
Dates:
Submitted: | Aug 1, 2018 |
Published print: | Dec 1, 2018 |
Published online: | Mar 5, 2019 |
Identifiers:
Web of science: | WOS:000460478800012 |
Scopus: | 2-s2.0-85062637955 |
Elibrary: | 38705347 |
OpenAlex: | W2920779455 |