Deep oxidation of methane on palladium catalysts on suppliers ZrО2, СеО2, ZrО2-СеО2, СеО2-CuО on stainless steel prepared with the method of plasma drawing

Deep oxidation of methane on palladium catalysts on suppliers ZrО2, СеО2, ZrО2-СеО2, СеО2-CuО on stainless steel prepared with the method of plasma drawing Full article

Conference

5-ая международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства"
25-30 Apr 2015 , Омск

Journal

Procedia Engineering
ISSN: 1877-7058

Output data

Year: 2015, Volume: 113, Pages: 124-130 Pages count : 7 DOI: 10.1016/j.proeng.2015.07.303

Tags

deep oxidation of methane; [Pd(NH3)4](NO3)2; plasma dusting; the scanning electronic microscopy; rentgeno-phase analysis

Authors

Borisov V.A. ^1,2 , Nedosekov A.S. ¹ , Sigayeva S.S. ¹ , Suprunov G.I. ⁴ , Vershinin V.I. ³ , Tsyrulnikov P.G. ¹

Affiliations

1	Institute of Hydrocarbon Processing SB RAS, 54, Neftezavodskaja. St., Omsk 644040, Russian Federation
2	Omsk State Technical University, 11, Mira Pr., Omsk 644050, Russian Federation
3	Omsk State University of F.M. Dostoyevsky, 55A, Mira Pr., Omsk 644077, Russian Federation
4	JSC Omsk scientific research institute of technology and organization of production of engines,283, Bogdan Khmelnytsky St., Omsk 644021, Russian Federation

The influence of the nature and the maintenance of the secondary supplier, the contents and the nature of the predecessor of palladium on catalytic activity of Pd/MeOx/Ni-Al/HC catalysts in the reaction of deep oxidation of methane is considered in the work. The secondary supplier was put with the method of a plasma dusting. It is defined that the best predecessor of palladium is [Pd(NH3)4](NO3)2. The minimum concentration of palladium necessary for achievement of full oxidation of methane on the best samples is 0.25%. It is shown that with the increase in the maintenance of ZrO2 the activity grows in catalysts. All catalysts are characterized by the XRF method. The most active sample of Pd/CeO2-ZrO2/Ni-Al/HC is additionally investigated by the method of the scanning electronic microscopy.

Borisov V.A. , Nedosekov A.S. , Sigayeva S.S. , Suprunov G.I. , Vershinin V.I. , Tsyrulnikov P.G.
Deep oxidation of methane on palladium catalysts on suppliers ZrО2, СеО2, ZrО2-СеО2, СеО2-CuО on stainless steel prepared with the method of plasma drawing

Procedia Engineering. 2015. V.113. P.124-130. DOI: 10.1016/j.proeng.2015.07.303 WOS Scopus РИНЦ OpenAlex

Full text from publisher

Published online:

Aug 31, 2015

Web of science:	WOS:000380445300021
Scopus:	2-s2.0-84984916646
Elibrary:	27570538
OpenAlex:	W1054392220

DB	Citing
Web of science	5
Scopus	4
Elibrary	6
OpenAlex	4