In Situ Study of the Interaction between tertButyl Chloride and Aluminum Activated with Liquid In–Ga Eutectic Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2010, Volume: 51, Number: 3, Pages: 354-358 Pages count : 5 DOI: 10.1134/S0023158410030043 | ||||
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Abstract:
The interaction between tert-butyl chloride and activated aluminum was studied by attenuated total reflectance Fourier transform infrared spectroscopy near room temperature (18–25°C). A long induction period of ~240–260 min was observed. The ionic aluminum chloride complexes [AlnCl3n+1]– (n = 1, 2) and the molecular species AlCl3 were identified at the activated aluminum/tert-butyl chloride interface during the reaction. The formation of the AlCl4- ion in the liquid medium and the presence of the same ion and a molecular AlCl3–tert-butyl chloride complex in the resinous products of the reaction were confirmed by 27Al NMR spectroscopy. The reaction products were analyzed qualitatively by GC/MS. The reactivities of activated aluminum and anhydrous aluminum chloride toward tert-butyl chloride under the same conditions were compared. A distinctive feature of the interaction activated aluminum and tert-butyl chloride is the dominant formation of the AlCl4- ion. By contrast, the interaction between aluminum chloride and tert-butyl chloride yields the polynuclear ion Al2Cl7- and, likely,Al3Cl10- .
Cite:
Arbuzov A.B.
, Drozdov V.A.
, Likholobov V.A.
, Trenikhin M.V.
, Talsi V.P.
, Kudrya E.N.
In Situ Study of the Interaction between tertButyl Chloride and Aluminum Activated with Liquid In–Ga Eutectic
Kinetics and Catalysis. 2010. V.51. N3. P.354-358. DOI: 10.1134/S0023158410030043 WOS Scopus РИНЦ OpenAlex
In Situ Study of the Interaction between tertButyl Chloride and Aluminum Activated with Liquid In–Ga Eutectic
Kinetics and Catalysis. 2010. V.51. N3. P.354-358. DOI: 10.1134/S0023158410030043 WOS Scopus РИНЦ OpenAlex
Original:
Арбузов А.Б.
, Дроздов В.А.
, Лихолобов В.А.
, Тренихин М.В.
, Талзи В.П.
, Кудря Е.Н.
Исследование in situ взаимодействия трет-бутилхлорида с алюминием, активированным жидкой эвтектикой In–Ga
Кинетика и катализ. 2010. Т.51. №3. С.375-379. РИНЦ
Исследование in situ взаимодействия трет-бутилхлорида с алюминием, активированным жидкой эвтектикой In–Ga
Кинетика и катализ. 2010. Т.51. №3. С.375-379. РИНЦ
Dates:
| Submitted: | May 27, 2009 |
| Published print: | Jun 1, 2010 |
| Published online: | Jun 24, 2010 |
Identifiers:
| Web of science: | WOS:000281104600004 |
| Scopus: | 2-s2.0-77955756270 |
| Elibrary: | 15332993 |
| OpenAlex: | W2041126502 |