Approaches to the synthesis of Pd/C catalysts with controllable activity and selectivity in hydrogenation reactions Научная публикация
| Журнал |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Вых. Данные | Год: 2020, Том: 357, Страницы: 152-165 Страниц : 14 DOI: 10.1016/j.cattod.2019.03.023 | ||
| Ключевые слова | Palladium catalysts, Carbon support, Catalytic hydrogenation, Controllable activity, Controllable selectivity | ||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Министерство науки и высшего образования Российской Федерации | V.47.1.3 |
| 2 | Министерство науки и высшего образования Российской Федерации | V. 47 |
Реферат:
Carbon-supported palladium catalysts are widely used for hydrogenation of various organic compounds in the fine chemical industry. The nanoscale geometry and electronic structure of supported Pd nanoparticles play a crucial role in providing the necessary catalytic properties. To improve catalytic activity and selectivity of Pd nanoparticles, it is possible to fine tune their intrinsic properties (e.g., size and oxidation state) by controlling the chemical transformations at different stages of catalyst preparation. Recent years have seen considerable advancement in developing new catalyst preparation techniques as well as in understanding the mechanism of active site formation. This review summarizes some of the existing approaches to regulating the catalytic properties of carbon-supported palladium by variation of the carbon support, the composition of palladium precursor and its reduction conditions, as well as the addition of a second active metal. The data presented may be useful for researchers developing efficient Pd/C catalysts for hydrogenation of polyfunctional organic compounds.
Библиографическая ссылка:
Mironenko R.M.
, Belskaya O.B.
, Likholobov V.A.
Approaches to the synthesis of Pd/C catalysts with controllable activity and selectivity in hydrogenation reactions
Catalysis Today. 2020. V.357. P.152-165. DOI: 10.1016/j.cattod.2019.03.023 WOS Scopus РИНЦ OpenAlex
Approaches to the synthesis of Pd/C catalysts with controllable activity and selectivity in hydrogenation reactions
Catalysis Today. 2020. V.357. P.152-165. DOI: 10.1016/j.cattod.2019.03.023 WOS Scopus РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 27 окт. 2018 г. |
| Принята к публикации: | 9 мар. 2019 г. |
| Опубликована online: | 13 мар. 2019 г. |
| Опубликована в печати: | 1 нояб. 2020 г. |
Идентификаторы БД:
| Web of science: | WOS:000579549200018 |
| Scopus: | 2-s2.0-85062991915 |
| РИНЦ: | 38704456 |
| OpenAlex: | W2921925827 |