Synthesis and study of Ru–Ba–Cs/Sibunit ternary catalysts for ammonia synthesis

Synthesis and study of Ru–Ba–Cs/Sibunit ternary catalysts for ammonia synthesis Научная публикация

Журнал

Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296

Вых. Данные

Год: 2017, Том: 90, Номер: 6, Страницы: 887-894 Страниц : 8 DOI: 10.1134/S1070427217060088

Авторы

Iost K. N. ¹ , Temerev V. L. ¹ , Smirnova N. S. ² , Shlyapin D. A. ¹ , Borisov V. A. ^1,3 , Muromtsev I. V. ¹ , Trenikhin M. V. ¹ , Kireeva T. V. ¹ , Shilova A. V. ¹ , Tsyrul’nikov P. G. ¹

Организации

1	Institute for Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences, Omsk, Russia
2	Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
3	Omsk State Technical University, Omsk, Russia

Ru–Ba–Cs/Sibunit ternary catalysts were synthesized. Their activity in ammonia synthesis and the thermal stability of the support in a reducing atmosphere at elevated temperature depend on the molar ratio of the promoters. The results of studies using physical methods suggest that cesium predominantly interacts with the support, acting as an electronic promoter, whereas barium is a structural promoter. The synergistic action of the promoters at increased barium content of the catalyst was revealed. The highest activity in ammonia synthesis, 34.5 mLNH3 gcat –1 h–1, was reached for the 4% Ru–10.8% Ba–2.6% Cs/Sibunit catalyst.

Iost K.N. , Temerev V.L. , Smirnova N.S. , Shlyapin D.A. , Borisov V.A. , Muromtsev I.V. , Trenikhin M.V. , Kireeva T.V. , Shilova A.V. , Tsyrul’nikov P.G.
Synthesis and study of Ru–Ba–Cs/Sibunit ternary catalysts for ammonia synthesis
Russian Journal of Applied Chemistry. 2017. V.90. N6. P.887-894. DOI: 10.1134/S1070427217060088 WOS Scopus РИНЦ OpenAlex

Иост К.Н. , Темерев В.Л. , Смирнова Н.С. , Шляпин Д.А. , Борисов В.А. , Муромцев И.В. , Тренихин М.В. , Киреева Т.В. , Шилова А.В. , Цырульников П.Г.
Синтез и исследование трехкомпонентных катализаторов Ru–Ba–Cs/сибунит для процесса синтеза аммиака
Журнал прикладной химии. 2017. Т.90. №6. С.731-739. РИНЦ

Опубликована в печати:	1 июн. 2017 г.
Поступила в редакцию:	21 июл. 2017 г.
Опубликована online:	25 окт. 2017 г.

Web of science:	WOS:000413662000008
Scopus:	2-s2.0-85032263574
РИНЦ:	31127212
OpenAlex:	W2766025837

БД	Цитирований
Web of science	15
Scopus	17
РИНЦ	7
OpenAlex	20