Реферат: The effect of zirconia precursor in Pt-containing WO3/ZrO2 catalysts on isomerization of n-heptane was studied. Samples synthesized with zirconium sulfate as a ZrO2 precursor were shown to be more active in comparison with those synthesized from zirconium oxychloride. The enhanced activity of samples synthesized from zirconium sulfate is caused by a residual (1–1.3 wt. %) content of sulfate ions in the catalysts, which increases the catalyst acidity; as a result, the samples synthesized with zirconium oxychloride as a ZrO2 precursor are more selective. Characteristics of WO3/ZrO2 catalysts containing Pt or Pd as a metallic component were compared in n-heptane isomerization. The use of Pd as a hydrogenating component of tungstated zirconia catalysts was shown to improve the performance of n-heptane isomerization in comparison with the catalysts where the metallic component was represented by Pt.

Библиографическая ссылка: Shkurenok V.A. , Smolikov M.D. , Yablokova S.S. , Kir’yanov D.I. , Kayumova T.R. , Muromtsev I.V. , Belyi A.S.
Synthesis and study of Pt(Pd)-containing WO3/ZrO2 catalysts for isomerization of n-heptane
AIP Conference Proceedings. 2017. V.1876. 020005 :1-7. DOI: 10.1063/1.4998825 WOS Scopus РИНЦ OpenAlex

Идентификаторы БД:

Web of science:	WOS:000410776900005
Scopus:	2-s2.0-85028885982
РИНЦ:	31065037
OpenAlex:	W2745867035

Цитирование в БД:

БД	Цитирований
Scopus	1
Web of science	1
OpenAlex	1

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