A study of Pd/SO4/ZrO2/Al2O3 catalysts in n-hexane isomerization

A study of Pd/SO4/ZrO2/Al2O3 catalysts in n-hexane isomerization Full article

Conference

7-ая международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства"
24-28 Apr 2017 , Омск

Journal

AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616

Output data

Year: 2017, Volume: 1876, Article number : 020009, Pages count : 7 DOI: 10.1063/1.4998829

Authors

Dzhikiya O. V. ¹ , Smolikov M. D. ^1,2 , Kazantsev K. V. ¹ , Yablokova S. S. ¹ , Kireeva T. V. ¹ , Paukshtis E. A. ³ , Gulyaeva T. I. ¹ , Belyi A. S. ^1,2

Affiliations

1	Institute of Hydrocarbons Processing SB RAS
2	Omsk State Technical University
3	Boreskov Institute of Catalysis SB RAS

Funding (1)

Russian Foundation for Basic Research

16-43-550196 r_a

The effect of palladium concentration in a range from 0.02 to 1.6 wt.% on characteristics of n-hexane isomerization was studied. The (O2-Hchem) titration and O2 chemisorption study revealed that palladium in Pd/SO4/ZrO2/Al2O3 systems adsorbs hydrogen in a ratio H/Pds = 1.13-1.65 at./at. Investigation of the charge state of the metal by IR spectroscopy of adsorbed CO showed the presence of both the metallic (Pd0) and charged palladium species. Pd/SO4/ZrO2/Al2O3 catalysts with charged palladium atoms exhibit high activity and selectivity in n-hexane isomerization.

Dzhikiya O.V. , Smolikov M.D. , Kazantsev K.V. , Yablokova S.S. , Kireeva T.V. , Paukshtis E.A. , Gulyaeva T.I. , Belyi A.S.
A study of Pd/SO4/ZrO2/Al2O3 catalysts in n-hexane isomerization
AIP Conference Proceedings. 2017. V.1876. 020009 :1-7. DOI: 10.1063/1.4998829 WOS Scopus OpenAlex

Published online:

Aug 23, 2017

Web of science:	WOS:000410776900009
Scopus:	2-s2.0-85028894254
OpenAlex:	W2747831608

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Scopus	1
Web of science	1
OpenAlex	1