Supported Sulfated Zirconia Catalysts for Isomerization of n-hexane Full article
Conference |
6-я международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства" 25-30 Apr 2016 , Омск |
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Journal |
Procedia Engineering
ISSN: 1877-7058 |
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Output data | Year: 2016, Volume: 152, Pages: 87-93 Pages count : 7 DOI: 10.1016/j.proeng.2016.07.634 | ||||
Tags | Isomerization, sulfated zirconia, supported catalysts, platinum | ||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 16-43-550196 r_a |
2 | Federal Agency for Scientific Organizations | V.46.2.8 |
Abstract:
Sulfated zirconia catalysts supported on SiO2 and Al2O3 were prepared and studied. Phase composition of the catalysts, acidic properties in CO adsorption, and textural characteristics were assessed. Activity of the catalysts in isomerization of n-hexane was measured. Alumina was shown to be a promising support for the synthesis of such catalysts. A new step of additional sulfation after platinum deposition was proposed for the synthesis of alumina-supported catalysts. It was found that strong Lewis acid sites with CO absorption bands at 2210 and 2224 cm-1 are formed in the catalysts. The yield of the sum of hexane isomers for the alumina-supported catalysts reached 80 wt.%.
Cite:
Bikmetova L.I.
, Smolikov M.D.
, Zatolokina E.V.
, Kazantsev K.V.
, Tregubenko V.Y.
, Belyi A.S.
Supported Sulfated Zirconia Catalysts for Isomerization of n-hexane
Procedia Engineering. 2016. V.152. P.87-93. DOI: 10.1016/j.proeng.2016.07.634 WOS Scopus РИНЦ OpenAlex
Supported Sulfated Zirconia Catalysts for Isomerization of n-hexane
Procedia Engineering. 2016. V.152. P.87-93. DOI: 10.1016/j.proeng.2016.07.634 WOS Scopus РИНЦ OpenAlex
Files:
Full text from publisher
Dates:
Published online: | Aug 10, 2016 |
Identifiers:
Web of science: | WOS:000383945400014 |
Scopus: | 2-s2.0-84985991139 |
Elibrary: | 27572320 |
OpenAlex: | W2505170054 |