Sciact
  • EN
  • RU

Synthesis of Carbon Materials via Mechanically Activated Dehydrochlorination of Polyvinyl Chloride Full article

Journal Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296
Output data Year: 2018, Volume: 91, Number: 11, Pages: 1830−1834 Pages count : DOI: 10.1134/S1070427218110137
Tags polyvinyl chloride, polyvinylenes, dehydrochlorination, mechanical activation, porous carbon materials, waste utilization
Authors Anikeeva I.V. 1 , Kryazhev Yu.G. 1 , Arbuzov A.B. 1 , Talzi V.P. 1 , Gulyaeva T.I. 1 , Drozdov V.A. 1
Affiliations
1 Institute of Hydrocarbon Processing Problems, Siberian Branch, Russian Academy of Sciences, Omsk

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation V.46.1.4

Abstract: Mechanically activated dehydrochlorination of polyvinyl chloride in the presence of lithium, potassium, and calcium hydroxides was studied. Short joint mechanical treatment of polyvinyl chloride with the above bases in a high-energy centrifugal planetary mill for 5–10 min ensures the formation of polymers with a conjugated double bond system (polyvinylenes). Their subsequent heat treatment at temperatures of up to 400°С yields amorphous carbon structures. Activation of the resulting material in a СО2 medium at 850°С results in the formation of a micro-, mesoporous carbon material with the prevalent mesopore volume. The results obtained can serve as a basis for the development of technologically acceptable procedures for polyvinyl chloride waste processing to obtain demanded carbon materials without dioxin formation.
Cite: Anikeeva I.V. , Kryazhev Y.G. , Arbuzov A.B. , Talzi V.P. , Gulyaeva T.I. , Drozdov V.A.
Synthesis of Carbon Materials via Mechanically Activated Dehydrochlorination of Polyvinyl Chloride
Russian Journal of Applied Chemistry. 2018. V.91. N11. P.1830−1834. DOI: 10.1134/S1070427218110137 WOS Scopus РИНЦ OpenAlex
Original: Аникеева И.В. , Кряжев Ю.Г. , Арбузов А.Б. , Талзи В.П. , Гуляева Т.И. , Дроздов В.А.
Синтез углеродных материалов с использованием механоактивированного дегидрохлорирования поливинилхлорида
Журнал прикладной химии. 2018. Т.91. №11. С.1620-1625. DOI: 10.1134/S0044461818110129 РИНЦ OpenAlex
Dates:
Submitted: Jun 27, 2018
Published print: Nov 1, 2018
Published online: Feb 5, 2019
Identifiers:
Web of science: WOS:000457646400013
Scopus: 2-s2.0-85061696029
Elibrary: 38670023
OpenAlex: W2913373218
Citing:
DB Citing
Scopus 7
Web of science 6
OpenAlex 8
Altmetrics: