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Hydrogen Transfer in Transformations of Olefin and Thiophene Compounds for the Refining of Gasoline Fractions Full article

Journal Fuel Processing Technology
ISSN: 0378-3820
Output data Year: 2014, Volume: 128, Pages: 251-256 Pages count : 6 DOI: 10.1016/j.fuproc.2014.07.034
Tags Hydrogen transfer, Straight-run gasoline, Coke gasoline, Reduction of olefin and sulfur contents
Authors Potapenko Oleg V. 1 , Doronin Vladimir P. 1 , Sorokina Tatyana P. 1 , Likholobov Vladimir A. 1
Affiliations
1 Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences, Russian Federation

Abstract: Hydrogen transfer reactions in the transformations of mixtures of model hydrocarbons (hydrogen donors and acceptors) on zeolite catalysts were studied. Hydrogen donors were represented by various classes of hydrocarbons, and acceptors—by unsaturated (olefin) and thiophene compounds. The [H]-donor activity series of hydrocarbons was revealed. Strong differences in the transformation pathways of 1-hexene and 1-octene under the conditions of catalytic refining were demonstrated. A new method for the refining of low-rank gasoline fractions was proposed. The method is based on the hydrogen transfer reactions between hydrogen donor hydrocarbons and hydrogen acceptor hydrocarbons, which proceed without molecular hydrogen. The proposed method allows the simultaneous removal of sulfur (more than 95%) and unsaturated (more than 90%) compounds.
Cite: Potapenko O.V. , Doronin V.P. , Sorokina T.P. , Likholobov V.A.
Hydrogen Transfer in Transformations of Olefin and Thiophene Compounds for the Refining of Gasoline Fractions
Fuel Processing Technology. 2014. V.128. P.251-256. DOI: 10.1016/j.fuproc.2014.07.034 WOS Scopus РИНЦ OpenAlex
Dates:
Submitted: Jan 16, 2014
Accepted: Jul 22, 2014
Published online: Aug 9, 2014
Published print: Nov 30, 2014
Identifiers:
Web of science: WOS:000343389900028
Scopus: 2-s2.0-84907306318
Elibrary: 23990030
OpenAlex: W2075573629
Citing:
DB Citing
Web of science 8
Scopus 9
Elibrary 9
OpenAlex 25
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