Plasma electrolytic oxide coatings on silumin for oxidation CO

Plasma electrolytic oxide coatings on silumin for oxidation CO Full article

Conference

7-ая международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства"
24-28 Apr 2017 , Омск

Journal

AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616

Output data

Year: 2017, Volume: 1876, Article number : 020001, Pages count : 10 DOI: 10.1063/1.4998821

Authors

Borisov V.A. ^1,2 , Sigaeva S.S. ¹ , Anoshkina E.A. ¹ , Ivanov A.L. ⁴ , Litvinov P.V. ^4,5 , Vedruchenko V.R. ⁵ , Temerev V.L. ¹ , Arbuzov A.B. ¹ , Kuznetsov A.A. ⁵ , Mukhin V.A. ³ , Suprunov G.I. ⁶ , Chumychko I.A. ² , Shlyapin D.A. ¹ , Tsyrul’nikov P.G. ¹

Affiliations

1	Institute of Hydrocarbons Processing, SB RAS
2	Omsk State Technical University
3	Dostoevsky Omsk State University
4	Siberian State Automobile and Highway Academy (SibADI)
5	Omsk State Transport University
6	JSC Omsk Scientific-Research Institute of Technology and Organization of Engines Production

Some catalysts of CO oxidation on silumin alloy AK12M2, used for the manufacture of pistons for Russian cars were investigated. The catalysts were prepared by the method of plasma electrolytic oxidation of silumin in electrolytes of various compositions with further activation by the salts Ce, Cu, Co, Ni, Mn and Al. The catalytic tests were carried out in a flow reactor in a mixture of 1% CO and 99% air, with the temperature range of 25-500 °C. The most active catalysts in CO oxidation are those activated with Ce and Cu salts on silumin, treated for 3 hours in an electrolyte containing 4 g/l KOH, 40 g/l Na2B4O7 (conversion of CO is 93.7% at a contact time of 0.25 s). However, the catalysts obtained from silumin treated in the electrolyte containing 3 g/l KOH, 30 g/l Na2SiO3 are more suitable for practical usage. Because when the treatment time of those catalysts is 10 – 20 minutes it is possible to achieve comparable CO conversion. The morphology and composition of the catalysts were studied by the methods of a scanning electron microscope with energy-dispersive surface analysis and X-ray phase analysis. The surface of the non-activated sample consists of γ-Al2O3 and SiO2 particles, due to which the active components get attached to the support. CeO2 and CuO are present on the surface of the sample with the active component.

Borisov V.A. , Sigaeva S.S. , Anoshkina E.A. , Ivanov A.L. , Litvinov P.V. , Vedruchenko V.R. , Temerev V.L. , Arbuzov A.B. , Kuznetsov A.A. , Mukhin V.A. , Suprunov G.I. , Chumychko I.A. , Shlyapin D.A. , Tsyrul’nikov P.G.
Plasma electrolytic oxide coatings on silumin for oxidation CO
AIP Conference Proceedings. 2017. V.1876. 020001 :1-10. DOI: 10.1063/1.4998821 WOS Scopus OpenAlex

Web of science:	WOS:000410776900001
Scopus:	2-s2.0-85028855027
OpenAlex:	W2748803431

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