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Development of New Methods in Modern Selective Organic Synthesis: Preparation of Functionalized Molecules with Atomic Precision Review

Journal Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837
Output data Year: 2014, Volume: 83, Number: 10, Pages: 885-985 Pages count : 101 DOI: 10.1070/RC2014v83n10ABEH004471
Authors Ananikov V P 1,2 , Khemchyan L L 1 , Ivanova Yu V 1 , Bukhtiyarov V I 3,4 , Sorokin A M 3 , Prosvirin I P 3 , Vatsadze S Z 5 , Medvedʹko A V 5 , Nuriev V N 5 , Dilman A D 1 , Levin V V 1 , Koptyug I V 4,6 , Kovtunov K V 4,6 , Zhivonitko V V 4,6 , Likholobov V A 7 , Romanenko A V 3 , Simonov P A 3,4 , Nenajdenko V G 5,8 , Shmatova O I 5 , Muzalevskiy V M 5 , Nechaev M S 5,9 , Asachenko A F 9 , Morozov O S 9 , Dzhevakov P B 9 , Osipov S N 8 , Vorobyeva D V 8 , Topchiy M A 8 , Zotova M A 8 , Ponomarenko S A 5,10 , Borshchev O V 10 , Luponosov Yu N 10 , Rempel A A 11,12 , Valeeva A A 11,12 , Stakheev A Yu 1 , Turova O V 1 , Mashkovsky I S 1 , Sysolyatin S V 13 , Malykhin V V 13 , Bukhtiyarova G A 3 , Terentʹev A O 1 , Krylov I B 1
Affiliations
1 N D Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prosp. 47, 119991 Moscow, Russian Federation
2 St Petersburg State University, Universitetskaya nab. 7 ± 9, 199034 St Petersburg, Russian Federation
3 G K Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, prosp. Akademika Lavrentieva 5, 630090 Novosibirsk, Russian Federation
4 Novosibirsk State University, ul. Pirogova 2, 630090 Novosibirsk, Russian Federation
5 Department of Chemistry, M V Lomonosov Moscow State University, Leninskie Gory 1, build. 3, 119991 Moscow, Russian Federation
6 International Tomography Center, Siberian Branch of the Russian Academy of Sciences, ul. Institutskaya 3a, 630090 Novosibirsk, Russian Federation
7 Institute of Hydrocarbon Processing, Siberian Branch of the Russian Academy of Sciences, ul. Neftezavodskaya 54, 644040 Omsk, Russian Federation
8 A N Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991 Moscow, Russian Federation
9 A V Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky prosp. 29, 119991 Moscow, Russian Federation
10 N S Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, ul. Profsoyuznaya 70, 117393 Moscow, Russian Federation
11 Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, ul. Pervomaiskaya 91, 620990 Ekaterinburg, Russian Federation
12 Ural Federal University named after the First President of Russia B N Yeltsin, ul. Mira 19, 620002 Ekaterinburg, Russian Federation
13 Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, ul. Socialisticheskaya 1, 659322 Biysk, Altai Krai, Russian Federation

Abstract: The challenges of the modern society and the growing demand of high-technology sectors of industrial production bring about a new phase in the development of organic synthesis. A cutting edge of modern synthetic methods is introduction of functional groups and more complex structural units into organic molecules with unprecedented control over the course of chemical transformation. Analysis of the state-of-the-art achievements in selective organic synthesis indicates the appearance of a new trend — the synthesis of organic molecules, biologically active compounds, pharmaceutical substances and smart materials with absolute selectivity. Most advanced approaches to organic synthesis anticipated in the near future can be defined as 'atomic precision' in chemical reactions. The present review considers selective methods of organic synthesis suitable for transformation of complex functionalized molecules under mild conditions. Selected key trends in the modern organic synthesis are considered including the preparation of organofluorine compounds, catalytic cross-coupling and oxidative cross-coupling reactions, atom-economic addition reactions, methathesis processes, oxidation and reduction reactions, synthesis of heterocyclic compounds, design of new homogeneous and heterogeneous catalytic systems, application of photocatalysis, scaling up synthetic procedures to industrial level and development of new approaches to investigation of mechanisms of catalytic reactions.
Cite: Ananikov V.P. , Khemchyan L.L. , Ivanova Y.V. , Bukhtiyarov V.I. , Sorokin A.M. , Prosvirin I.P. , Vatsadze S.Z. , Medvedʹko A.V. , Nuriev V.N. , Dilman A.D. , Levin V.V. , Koptyug I.V. , Kovtunov K.V. , Zhivonitko V.V. , Likholobov V.A. , Romanenko A.V. , Simonov P.A. , Nenajdenko V.G. , Shmatova O.I. , Muzalevskiy V.M. , Nechaev M.S. , Asachenko A.F. , Morozov O.S. , Dzhevakov P.B. , Osipov S.N. , Vorobyeva D.V. , Topchiy M.A. , Zotova M.A. , Ponomarenko S.A. , Borshchev O.V. , Luponosov Y.N. , Rempel A.A. , Valeeva A.A. , Stakheev A.Y. , Turova O.V. , Mashkovsky I.S. , Sysolyatin S.V. , Malykhin V.V. , Bukhtiyarova G.A. , Terentʹev A.O. , Krylov I.B.
Development of New Methods in Modern Selective Organic Synthesis: Preparation of Functionalized Molecules with Atomic Precision
Russian Chemical Reviews. 2014. V.83. N10. P.885-985. DOI: 10.1070/RC2014v83n10ABEH004471 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Анаников В.П. , Хемчян Л.Л. , Иванова Ю.В. , Бухтияров В.И. , Сорокин А.М. , Просвирин И.П. , Вацадзе С.З. , Медведько А.В. , Нуриев В.Н. , Дильман А.Д. , Левин В.В. , Коптюг И.В. , Ковтунов К.В. , Живонитко В.В. , Лихолобов В.А. , Романенко А.В. , Симонов П.А. , Ненайденко В.Г. , Шматова О.И. , Музалевский В.М. , Нечаев М.С. , Асаченко А.Ф. , Морозов О.С. , Джеваков П.Б. , Осипов С.Н. , Воробьева Д.В. , Топчий М.А. , Зотова М.А. , Пономаренко С.А. , Борщев О.В. , Лупоносов Ю.Н. , Ремпель А.А. , Валеева А.А. , Стахеев А.Ю. , Турова О.В. , Машковский И.С. , Сысолятин С.В. , Малыхин В.В. , Бухтиярова Г.А. , Терентьев А.О. , Крылов И.Б.
Развитие методологии современного селективного органического синтеза: получение функционализированных молекул с атомарной точностью
Успехи химии. 2014. Т.83. №10. С.885-985. РИНЦ
Dates:
Submitted: May 29, 2014
Published print: Oct 30, 2014
Published online: Nov 8, 2014
Identifiers:
Web of science: WOS:000344941600002
Scopus: 2-s2.0-84907452759
Elibrary: 23990954
Chemical Abstracts: 2014:2092188
Chemical Abstracts (print): 162:189755
OpenAlex: W2032622014
Citing:
DB Citing
Web of science 194
Scopus 205
Elibrary 147
OpenAlex 199
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