Effect of Alumina Support Modification on the State of the Active Surface of Alumina–Nickel–Molybdenum Catalysts for Ethylene Conversion to Propylene

Effect of Alumina Support Modification on the State of the Active Surface of Alumina–Nickel–Molybdenum Catalysts for Ethylene Conversion to Propylene Научная публикация

Журнал

Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555

Вых. Данные

Год: 2026, Том: 18, Номер: 2, Страницы: 149–158 Страниц : 10 DOI: 10.1134/S2070050426700091

Ключевые слова

nickel oxide, molybdenum oxide, alumina, modification, ethylene, propylene, dimerization, metathesis

Авторы

Karpova T.R. ¹ , Lavrenov A.V. ¹ , Moiseenko M.A. ¹ , Gulyaeva T.I. ¹ , Arbuzov A.B. ¹ , Gorbunova O.V. ¹ , Muromtsev I.V. ¹

Организации

1	Center for New Chemical Technologies, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Информация о финансировании (1)

Министерство науки и высшего образования Российской Федерации

FWUR-2024-0039

Nickel and molybdenum oxide catalysts synthesized using cation- and anion-modified alumina as a support (Na2O–Al2O3, MgO–Al2O3, Al2O3–Al2O3, ZrO2–Al2O3, B2O3–Al2O3, SO4^2- –Al2O3) were studied. Data on the effect of support surface modification on the physicochemical properties and activity of the catalysts in ethylene conversion to propylene were obtained. It was shown that anionic modification (B2O3– Al2O3, SO4^2- –Al2O3) improves catalyst activity catalyst activity due to the formation of octahedrally coordinated Ni2+ cations bound to the surface acid sites of the support. Cationic modification (Na2O–Al2O3, MgO–Al2O3, Al2O3–Al2O3, ZrO2–Al2O3), conversely, suppresses the development of ethylene conversion reactions due to a lower content of medium-strength and strong acid sites, which determine the strength of interaction with nickel cations, on the surface of these supports. The maximum propylene yield of 51–52 wt % is provided by catalysts based on a borate-containing support and unmodified alumina. They are characterized by the presence of highly dispersed species of polymolybdate compounds and medium-strength Brønsted acid sites on their surface.

Karpova T.R. , Lavrenov A.V. , Moiseenko M.A. , Gulyaeva T.I. , Arbuzov A.B. , Gorbunova O.V. , Muromtsev I.V.
Effect of Alumina Support Modification on the State of the Active Surface of Alumina–Nickel–Molybdenum Catalysts for Ethylene Conversion to Propylene
Catalysis in Industry. 2026. V.18. N2. P.149–158. DOI: 10.1134/S2070050426700091

Карпова Т.Р. , Лавренов А.В. , Моисеенко М.А. , Гуляева Т.И. , Арбузов А.Б. , Горбунова О.В. , Муромцев И.В.
Влияние модифицирования алюмооксидного носителя на состояние активной поверхности алюмоникельмолибденовых катализаторов превращения этилена в пропилен
Катализ в промышленности. 2025. Т.25. №4. С.71-81. DOI: 10.18412/1816-0387-2025-4-71-81 РИНЦ OpenAlex

Поступила в редакцию:	28 янв. 2025 г.
Принята к публикации:	26 мар. 2025 г.

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