Pt/BEA–Al2O3 catalysts for the isomerization of benzene/heptane mixtures. I: Optimizing the support’s composition Full article
| Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2017, Volume: 9, Number: 1, Pages: 48-53 Pages count : 6 DOI: 10.1134/s2070050417010032 | ||||
| Tags | BEA, benzene hydroisomerization, beta zeolite, n-heptane isomerization, platinum catalysts | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 46.2.4 |
| 2 | Federal Agency for Scientific Organizations | V.46.2.8 |
Abstract:
Pt/BEA–Al2O3 catalysts for the hydroisomerization of benzene-containing gasoline fractions are
studied using a model feedstock (20% benzene and 80% n-heptane). The catalysts are prepared by varying the zeolite content from 5 to 70 wt % at a constant Pt loading of 0.3 wt % in all samples, with an aqueous H2PtCl6 solution being used as the Pt precursor. The acid properties of the samples are studied by means of temperature-programmed desorption (TPD). The effect of the support’s zeolite/binder ratio on the activity of the catalysts is determined: an increase in the zeolite content raises the system’s acidity and shifts the range of the reaction toward lower temperatures. The optimum zeolite/binder ratio is found to be 30% BEA/70% Al2O3. Changing the SiO2/Al2O3 ratio of the zeolite from 25 to 40 is shown to have no noticeable effect on catalyst activity. The use of the catalysts supported on 30% BEA/70% Al2O3 in the hydroisomerization of benzenecontaining gasoline fractions can be recommended for improving environmental performance.
Cite:
Belopukhov E.A.
, Kalashnikov I.M.
, Smolikov M.D.
, Kir’yanov D.I.
, Gulyaeva T.I.
, Belyi A.S.
Pt/BEA–Al2O3 catalysts for the isomerization of benzene/heptane mixtures. I: Optimizing the support’s composition
Catalysis in Industry. 2017. V.9. N1. P.48-53. DOI: 10.1134/s2070050417010032 WOS Scopus РИНЦ OpenAlex
Pt/BEA–Al2O3 catalysts for the isomerization of benzene/heptane mixtures. I: Optimizing the support’s composition
Catalysis in Industry. 2017. V.9. N1. P.48-53. DOI: 10.1134/s2070050417010032 WOS Scopus РИНЦ OpenAlex
Original:
Белопухов Е.А.
, Калашников И.М.
, Смоликов М.Д.
, Кирьянов Д.И.
, Гуляева Т.И.
, Белый А.С.
Катализаторы Pt/BEA–Al2O3 в реакции гидроизомеризации смеси бензол – гептан: i. оптимизация состава носителя
Катализ в промышленности. 2016. Т.16. №5. С.60-65. DOI: 10.18412/1816-0387-2016-5-60-65 РИНЦ OpenAlex
Катализаторы Pt/BEA–Al2O3 в реакции гидроизомеризации смеси бензол – гептан: i. оптимизация состава носителя
Катализ в промышленности. 2016. Т.16. №5. С.60-65. DOI: 10.18412/1816-0387-2016-5-60-65 РИНЦ OpenAlex
Dates:
| Submitted: | May 8, 2016 |
| Published print: | Jan 1, 2017 |
| Published online: | Apr 7, 2017 |
Identifiers:
| Web of science: | WOS:000423241100007 |
| Scopus: | 2-s2.0-85017150979 |
| Elibrary: | 29515072 |
| OpenAlex: | W2604503593 |