Ethylene Conversion to Propylene over a NiO–MoO3/Al2O3 Catalyst: Effect of Conditions and Kinetics of the Process

Ethylene Conversion to Propylene over a NiO–MoO3/Al2O3 Catalyst: Effect of Conditions and Kinetics of the Process Научная публикация

Журнал

Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555

Вых. Данные

Год: 2025, Том: 17, Номер: 3, Страницы: 288–297 Страниц : 10 DOI: 10.1134/S2070050425700199

Ключевые слова

nickel oxide, molybdenum oxide, alumina, ethylene, propylene, dimerization, metathesis

Авторы

Karpova T.R. ¹ , Lavrenov A.V. ¹ , Moiseenko M.A. ¹ , Potapenko O.V. ¹ , Koveza V.A. ¹ , Buluchevskii E.A. ¹ , Arbuzov A.B. ¹ , Vasilevich A.V. ¹

Организации

1	Center of New Chemical Technologies, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Информация о финансировании (1)

Министерство науки и высшего образования Российской Федерации

FWUR-2024-0039

The effect of the conditions of ethylene conversion to propylene on the product yield and the activity and stability of a NiO–MoO3/Al2O3 catalyst has been studied. Tests in a flow reactor with a fixed catalyst bed at temperatures of 100–250°C, near-atmospheric pressure, and an ethylene weight hourly space velocity of 0.25–2 h−1 have been conducted. It has been found that the maximum propylene yield of 57 wt % is achieved at 150°C and 0.25 h−1. The ethylene conversion reaches 89%. A kinetic model of the process to describe the formation of the main reaction products has been proposed. It has been shown that, during ethylene conversion, carbon deposits are formed on the surface of the catalysts; when the temperature and contact time are increased, the amount of deposits grows, and the oxidation state of molybdenum atoms changes from +6 to +4/+5.

Karpova T.R. , Lavrenov A.V. , Moiseenko M.A. , Potapenko O.V. , Koveza V.A. , Buluchevskii E.A. , Arbuzov A.B. , Vasilevich A.V.
Ethylene Conversion to Propylene over a NiO–MoO3/Al2O3 Catalyst: Effect of Conditions and Kinetics of the Process
Catalysis in Industry. 2025. V.17. N3. P.288–297. DOI: 10.1134/S2070050425700199

Карпова Т.Р. , Лавренов А.В. , Моисеенко М.А. , Потапенко О.В. , Ковеза В.А. , Булучевский Е.А. , Арбузов А.Б. , Василевич А.В.
Превращение этилена в пропилен на катализаторе NiO-MoO3/Al2O3. Влияние условий и кинетические закономерности процесса
Катализ в промышленности. 2024. Т.24. №6. С.60-69. DOI: 10.18412/1816-0387-2024-6-60-69 OpenAlex

Поступила в редакцию:	13 мая 2024 г.
Принята к публикации:	5 июл. 2024 г.

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