Catalytic Cracking of n-Dodecane over P-Modified MFI Zeolites Synthesized by Steam-Assisted Conversion: Effect of SiO2/Al2O3 Ratio

Catalytic Cracking of n-Dodecane over P-Modified MFI Zeolites Synthesized by Steam-Assisted Conversion: Effect of SiO2/Al2O3 Ratio Научная публикация

Журнал

Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532

Вых. Данные

Год: 2024, Том: 64, Номер: 9, Страницы: 1096-1105 Страниц : 10 DOI: 10.1134/S0965544124060203

Ключевые слова

zeolites, MFI, ZSM-5, modification with phosphorus, cracking of n-dodecane

Авторы

Bachurina D.O. ^1,2 , Giliazutdinova A.S. ³ , Potapenko O.V. ³ , Ivanova I.I. ^1,2

Организации

1	Lomonosov Moscow State University
2	Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
3	Center of New Chemical Technologies, Omsk Branch, Federal Research Center Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Информация о финансировании (2)

1	Министерство науки и высшего образования Российской Федерации	FWUR-2024-0039
2	Российский научный фонд	24-13-00103

The paper describes the physicochemical characterization and catalytic testing of MFI zeolites with different SiO2/Al2O3 ratios synthesized by steam-assisted crystallization (SAC) and modified with phosphorus (4 wt % loading). Their physicochemical properties were characterized by X-ray diffraction analysis, X-ray fluorescence analysis, scanning electron microscopy, low-temperature nitrogen adsorption, ammonia temperature-programmed desorption, and MAS NMR spectroscopy. Both the parent and P-modified MFI zeolites were then subjected to catalytic tests in cracking of n-dodecane. The yield of light olefins was enhanced only in two cases: when MFI zeolites with SiO2/Al2O3 ratios of 30–70 were modified with 4 wt % phosphorus and when parent MFI zeolites with SiO2/Al2O3 ratios of 100–220 were used. It was further found that, in terms of catalytic performance in the cracking of n-dodecane, the MFI zeolites synthesized by SAC were comparable to a commercially available MFI zeolite synthesized under hydrothermal conditions. Moreover, in contrast to the commercially available zeolite, phosphorus modification of the SAC-synthesized zeolite enhanced the yield of C2–C4 olefins.

Bachurina D.O. , Giliazutdinova A.S. , Potapenko O.V. , Ivanova I.I.
Catalytic Cracking of n-Dodecane over P-Modified MFI Zeolites Synthesized by Steam-Assisted Conversion: Effect of SiO2/Al2O3 Ratio
Petroleum Chemistry. 2024. V.64. N9. P.1096-1105. DOI: 10.1134/S0965544124060203 WOS РИНЦ OpenAlex

Бачурина Д.О. , Гилязутдинова А.С. , Потапенко О.В. , Иванова И.И.
Каталитический крекинг н-додекана на цеолитах MFI, полученных методом парофазной кристаллизации и модифицированных фосфором: влияние отношения SiO2/Al2O3
Современные молекулярные сита. 2024. Т.6. №2. С.36-45. DOI: 10.53392/27130304_2024_6_2_36 РИНЦ

Поступила в редакцию:	18 сент. 2024 г.
Принята к публикации:	28 окт. 2024 г.
Опубликована в печати:	19 дек. 2024 г.

Web of science:	WOS:001379986700001
РИНЦ:	79026742
OpenAlex:	W4405524732

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